锦纶用吸湿排汗整理剂的合成及应用-丝绸.DOCVIP

研究与技术 锦纶用吸湿排汗整理剂的合成及应用 杨 涛1,2，董雯风1,2，杨奇琴1,2，张 珏1,2，周向东1,2（1.现代丝绸国家工程实验室江苏 苏州 2151232.苏州大学 纺织与服装工程学院江苏 苏州 215021）摘要：以双端羧基丙二醇无规聚醚（CT-PPE）、己二胺（HDA）、己二酸（AA）为原料，通过缩聚反应，合成了一种聚酰胺聚醚共聚型吸湿排汗整理剂，并将其用于锦纶织物的吸湿排汗整理；通过FTIR、TG-DTA、GPC和SEM测试，表征了整理剂结构和性能。实验探讨了反应物物质的量比、温度、时间对整理剂吸湿和快干性能的影响。研究结果表明：当n（CT-PPE）n(AA)∶n(HDA)=1∶1∶1、温度230 、时间2 h时，整理后未水洗的锦纶织物润湿时间、回潮率和水分蒸发率分别为5.3 s、6.3%和46.5%，水洗10次后的锦纶织物润湿时间、回潮率和水分蒸发率分别为8.4 s、5.8%和41.3%，表明整理剂能赋予织物较耐久的吸湿和快干性。关键词：吸湿排汗；整理剂；聚醚；锦纶 中图分类号：T 文献标志码：A 文章编号： Synthesis and Applications of Auxiliary with Moisture Absorption and Sweat Discharging Properties for Polyamide Fabric YANG Tao1,2 DONG Wenfeng1,2, YANG Qiqin1,2, ZHANG Jue1,2, ZHOU Xiangdong*1,2 (1. National Engineering Laboratory for Modern Silk, Suzhou 215123, China; 2. College of Textile and Clothing Engineering, Soochow University, Suzhou 215021, China) Abstract: This study synthesizes a polyamide polyether copolymerized finishing agent with moisture absorption and sweat discharging properties through condensation polymerization with double-end carboxyl propylene glycol random polyether (CT-PPE), hexamethylenediamine (HDA) and adipic acid (AA) and uses it for moisture absorption and sweat discharging of chinlon fabrics; and characterizes the structure and performance of the finishing agent through FTIR, TG-DTA, GPC and SEM test. The experiment discusses the influence of quantity relative ratio, temperature and time of reactant substance on moisture absorption and quick-drying properties of finishing agent. The research result shows that the wetting time, moisture regain and water evaporation rate of unwashed chinlon fabric after finishing are respectively 5.3 s , 6.3% and 46.5% and those of chinlon fabric washed for 10 times are respectively 8.4 s, 5.8% and 41.3% when n(CT-PPE):n(AA):n(HDA)=1:1:1, temperature 230 ℃ and time 2 h. This shows that the finishing agent can provide fabrics with lasting moisture absorption and quick-drying properties. Key words: moisture absorption and sweat