1核燃料开発机构.pdf

日本原子力学会和文論文誌，  ( ) Vol. 5, No. 4, p. 268 281 2006 研 究 論 文 酸化物電解法 MOX 電解共析の反応解析 1, 1,† 2 1 佐藤 史紀 ，水口 浩司 ，中西 繁之 ，明珍 宗孝 Reaction Analysis of MOX Co-deposition in Oxide Electrowinning Process 1, 1,† 2 1 Fuminori SATO , Koji MIZUGUCHI , Shigeyuki NAKANISHI and Munetaka MYOCHIN 1   Japan Nuclear Cycle Development Institute Tokai Works, 4 33 Muramatsu, Tokai-mura, Naka-gun, Ibaraki 319 1194, Japan 2   Japan Atomic Power Company, 1 1 Kanda, Mitoshiro-cho, Chiyoda-ku, Tokyo 101 0053, Japan ( ) Received September 26, 2005 and accepted in revised form July 11, 2006 MOX co-deposition process, which is one of the main parts of oxide electrowinning process, was studied by both sides of examination and analysis. Parameter tests using U and Pu were performed as basic examination, and fundamen- tal data of the process such as polarization property of molten salt including U and Pu, current e‹ciency of electrolysis and PuO2 concentration in recovered deposit, etc . were acquired. In addition, to analyze the process behavior, especially polarization property at electrolysis, a reaction model considering Pu4 ＋, Pu3 ＋, UO22 ＋, UO2 ＋, PuO22 ＋ and PuO2 ＋ in molten NaCl 2CsCl salt was developed. The validity of this model was conˆrmed by comparison of the experimental