p204浓度对树脂中p204吸附量和浸渍树脂吸附vⅳ的影响.docVIP

P204浸渍树脂对钒的吸附性能研究 梁粱1，包申旭1,2,3，张一敏1,2,3，唐咏平1 （1.武汉理工大学 资源与环境工程学院，武汉 430070；2.矿物资源加工与环境湖北省重点实验室，武汉 430070； 3.钒资源高效利用湖北省协同创新中心，武汉 430070） 摘要：以L493多孔吸附树脂为载体，P204为萃取剂制备了P204浸渍树脂，对制备的浸渍树脂进行表征，确定了最佳萃取剂浓度为50%。采用静态吸附法考察了在硫酸体系中溶液pH、钒离子浓度、温度以及浸渍时间等因素对P204浸渍树脂吸附钒性能的影响。结果表明，浸渍树脂吸附V(Ⅳ)、V(Ⅴ)的最佳pH均为2.0；吸附V(Ⅳ)、V(Ⅴ)的等温吸附曲线均符合Langmuir等温吸附模型；V(Ⅳ)、V(Ⅴ)吸附平衡时间分别为18 h和14 h，准二级动力学方程可以较好描述浸渍树脂吸附V(Ⅳ)、V(Ⅴ)的过程。 关键词：P204；钒；吸附；浸渍树脂 中图分类号：TF841.3TQ425.23 文献标志码：A 文章编号：1007-7545（2015）11-0000-00 Adsorption Properties of Vanadium on P204 Impregnated Resins LIANG Liang1, BAO Shen-xu1,2,3, ZHANG Yi-min1,2,3, TANG Yong-ping1 (1. College of Resources and Environmental Engineering, Wuhan University of Technology, Wuhan 430070, China; 2. Hubei Key Laboratory of Mineral Resources Processing and Environment, Wuhan 430070, China; 3. Hubei Collaborative Innovation Center for High Efficient Utilization of Vanadium Resources, Wuhan 430070, China) Abstract: Solvent impregnated resins (SIRs) were prepared with L493 macroporous adsorption resins as carrier and P204 as extractant. SIRs were characterized and the optimum concentration of extractant is 50%. The effects of pH value of solution, vanadium concentration, temperature, and contact time on absorption of vanadium in sulfuric acid solutions with SIRs were investigated through static adsorption method. The results show that the optimum pH value for both adsorption of vanadium (Ⅳ) and vanadium (Ⅴ) is 2.0. The adsorption isotherms of vanadium (Ⅳ) and vanadium (Ⅴ) on SIRs are fit to Langmuir isotherm model. Adsorption equilibrium time for vanadium (Ⅳ) and vanadium (Ⅴ) is 18 h and 14 h respectively. Adsorption processes of vanadium (Ⅳ) and vanadium (Ⅴ) can be well described by pseudo-second order model. Key words: P204; vanadium; adsorption; solvent impregnated resin; dynamics 石煤钒储量约占我国钒总储量的87%[1]，石煤提钒越来越多到人们的关注[2]。由于钒在石煤中主要以类质同象形式赋存于云母类矿物晶格中[3]，通常采用酸浸工艺才能较好的浸出率，但在酸浸过程中大部分杂质离子也会随着钒一起被浸出，需要对酸浸液进行净化富集[4]，满足后续沉钒工艺的要求[5]。目前，通常采用溶剂萃取法和离子交换法对石煤酸浸液中的钒进行分离富集。溶剂萃取条件要求苛刻、操