SCH 4U英文资料.pdfVIP

SCH 4U Cycloalkanes, Alkenes, and Aromatics Text assignment: Remainder of Page 18 # 3 - 6 Page 21 # 7, 8 Page 22 # 1-4 (every other letter) Multiple Covalent Bonds Organic compound arrangements • Alkanes, alkenes, and alkynes Nomenclature or names of compounds • Alkanes Nomenclature - Alkenes • Alkanes Nomenclature of Alkenes and Cycloalkenes PAlkenes are named by finding the longest chain containing the double bond ... P and changing the name of the corresponding parent chain from ane to ene Nomenclature of Alkenes The compound is numbered to give one of the alkene carbons the lowest number Cycloalkene PThe double bond of a cylcoalkene must be in position 1 and 2 Alkenes and Alkynes PUnsaturated (contains one or more double or triple bonds) hydrocarbons PDouble and triple bonds are more reactive than single bonds PAlkenes (C H ) are also called olefins n 2n PAll atoms around the double bond are in a plane (flat) PAtoms around a triple bond are in a line Alkenes PMolecules containing a double bond can have geometric isomers PThere is no rotation around double bonds P2-butene can have cis and trans isomers PCis - same side of double bond PTrans - across the double bond H H H CH 3 C C C C H 3 C CH 3 H 3 C H cis-2-butene trans-2-butene Geometric isomers PCis: If two identical groups occur on the same side of the double bond Geometric isomers PTrans: If two identical groups occur on opposite sides of the double bond