半焦对臭氧氧化模拟苯酚焦化废水的催化研究.docVIP

论文题目：半焦对臭氧氧化模拟苯酚焦化废水的催化研究 专 业：化学工程与工艺本 科 生： (签名) 指导教师： (签名) 摘 要 半焦催化氧化技术对有机物具有特殊的降解能力和机理，在焦化废水处理方面寄予厚望。但目前，这一技术在国内外还处于开拓阶段。 本论文采用臭氧氧化技术和半焦/臭氧氧化技术对苯酚模拟焦化废水去除的效果进行了研究。考察了反应时间、苯酚初始浓度、温度、臭氧流量、半焦投入量及初始pH值等因素对苯酚去除率的影响。 研究的结果表明：在臭氧氧化处理苯酚废水的过程中，苯酚去除率随溶液pH增大而增大；初始pH值在碱性条件下，效果显著； 苯酚的初始浓度较小时，其去除效果较明显； 温度较低时，苯酚去除率随着温度的升高而增大，温度较高时再提高温度，苯酚去除率并非一直显著上升；随着臭氧浓度的增大，苯酚去除率增大，在0.5L/min时效果最为明显。 在臭氧氧化处理模拟苯酚废水所确定的最佳条件下，加入半焦对苯酚去除有较好的效果，苯酚去除率随着半焦投入量的增加而增加，未投入半焦时在反应3.5h后苯酚去除率为49.03%，投入0.1克反应3.5h后苯酚去除率为59.45%，投入1.0克时反应3.5h后苯酚去除率为70.01%。随着半焦加入量的增加，催化效果加强，半焦/臭氧氧化法使苯酚得到了很好的降解。 关 键 词：半焦，臭氧氧化，苯酚废水，半焦/臭氧氧化法 研究类型：应用研究型 Subject : Study on Phenol Wastewater by Coal Char and Ozonization Specialty : Chemical Engineering and Technology Name : Yang Yan (Signature)__________ Instructor : Cai Huiwu Liu Xiangrong Huang Jie Li Gang (Signature)__________ ABSTRACT Coal char catalytic oxidation has the special degradation and mechanism in organic compounds. However, this technology is still in the development stage at home and abroad. In this thesis, We us ozone oxidation and coal char / ozone oxidation technology to remove Phenol wastewater. The effects of reaction time, initial Phenol concentration, temperature, ozone flow rate, coal char in volume and the initial pH value and other factors on the removal rate of Phenol. The results of the study show that the removal rate of Phenol increased with the pH of value the solution in ozone oxidation process of phenol wastewater. Under alkaline conditions in the initial pH value, the effect was significant. Its removal effect was pronounced when the initial concentration of Phenol was small. When the temperature was lower, the removal rate of Phenol increased with the temperature. The removal rate of Phenol would not always a significant increase when the temperature was higher. With the increase of ozone concentration, the removal rate