对CNB改性煤沥青制备半焦和针状焦性质研究.PDFVIP

29 6 No.6 Vol.29 2015 12 Journal of Chemical Engineering of Chinese Universities Dec. 2015 1003-9015(2015)06-1445-06 3-CNB  , , , , ( , 030024) (coal tar pitch-CTP)3-(3-chloronitrobenzene, 3-CNB), TGFT-IR1H-NMR XRD (modified CTP,MCTP), β TI QIs 3-CNB Iar A 880/A 1600 1 H-NMR 3-CNB MCTP HβHγ Har Hα XRD MCTP d002 3-CNB CTP TQ522.65 A DOI 10.3969/j.issn.1003-9015.2015.06.023 Semi-Coke and Needle Coke Production with 3-Chloronitrobenzene Modified Coal Tar Pitch CHAI Yun-jie, SU Lei, CAO Qing, DONG Ya-wei, JIN Li-e (College of Chemistry and Chemical Engineering, Taiyuan University of Technology, Taiyuan 030024, China) Abstract: Coal tar pitch (CTP) is often modified to enhance its potential value. In this study, CTP was modified with 3-chloronitrobenzene (3-CNB), and p -methyl benzenesulfonic was used as the catalyst. The carbonization yield increases and the optical texture of the products show a long-range fibrous structure after modification. Viscosity, soft point, coking value, toluene insoluble (TI) and quinoline insolubles (QIs) originated from coking process were measured. The properties of the intermediate products (semi-coke and needle coke) were analyzed by TG, FT-IR, 1H-NMR and XRD. The results reveal that the viscosity and β-resin content of the modif