环境友好型聚天冬氨酸衍生物的合成及其阻垢性能-表面技术.pdf

摇摇摇 62 佟欣佳等摇 环境友好型聚天冬氨酸衍生物的合成及其阻垢性能 环境友好型聚天冬氨酸衍生物的合成及其阻垢性能 佟欣佳,柳鑫华,丁云飞,张雪明 (河北联合大学 轻工学院,唐山063000) 摇 摇 [摘摇 要]摇 利用马来酸酐热缩聚产物聚琥珀酰亚胺(PSI)和硫脲,合成了一种聚天冬氨酸衍生物。 优化了 PSI与硫脲的反应条件,通过红外光谱对聚天冬氨酸衍生物的结构进行了表征,考察了聚天冬氨酸衍生物的阻垢 性能,分析了其阻垢机制。 结果表明:以硫脲对PSI进行开环,当硫脲用量为1g,改性缩聚温度为100 益,反应时 间为2.5 h 时,获得改性PASP产品的阻垢效果最佳;红外光谱证明了硫脲的一个氨基与原支链上的羧基发生缩 合,生成酰胺键,在聚天冬氨酸侧链上增加了新的官能团;聚天冬氨酸衍生物用量为10 mg/ L 时,阻垢率可达到 90%以上。 [关键词]摇 聚天冬氨酸;开环改性;阻垢剂;阻垢性能 [中图分类号]TG174.42 摇 摇 摇 [文献标识码]A 摇 摇 摇 [文章编号]1001鄄3660(2013)05鄄0062鄄04 Synthesis of Friendly鄄to鄄environment Polyaspartic Acid Derivative and Its Characteristics in Scale Inhibition TONGXin鄄jia,LIUXin鄄hua,DING Yun鄄fei,ZHANGXue鄄ming (College of Light Industry,Hebei United University,Tangshan063000,China) [Abstract]摇 Polyaspartic acid derivative was synthesised with sulfourea (CSN) and polysuccinimide (PSI)that was the thermal condensation polymer of MA. The reaction condition of PSI and CSNwasoptimized. The product structurewas charac鄄 terized by FT鄄IR. And the scale inhibition properties and mechanism of CSN鄄PASP were studied.The result indicates that the scale inhibitionefficiencyof CSN鄄PASPisoptimuminCSNwith 1.0 gundertheconditionof 100 益 and2.5hwithCSNtoring opening of PSI. FT鄄IR provesthat amide bond was generated through aminos of sulfourea and carboxyls and the new functional groups are increased on the side chain. CSN鄄PASP with 10 mg/ L,the scale inhibition efficiency is up to90%. [Key words]摇 PASP;ring鄄opening to improve performance;scale inhibitor;scale inhibition properties [7] 摇 摇 聚天冬氨酸(PASP)是一种可生物降解、对环境友 等 在水体系中,以乙醇胺与聚琥珀酰亚胺(PSI)进 [1] [8] 好的新型高分子材料 ,其原料易得,价格不高,近年 行反应,合成了羟基改性的聚天冬氨酸;高利军等 在