新生亚硫酸钙在糖汁清净过程中的机理.pdf

※基础研究 食品科学 2017, Vol.38, No.23 39 新生亚硫酸钙在糖汁清净过程中的机理 1,2 1,2,* 1,2 向富友 ，李利军 ，程 昊 （1.广西科技大学生物与化学工程学院，广西 柳州 545006 ；2.广西糖资源绿色加工重点实验室，广西 柳州 545006 ） 摘  要：以新生CaSO3 的形貌和结构为出发点，探讨了其在糖汁清净过程中的作用机理。新生CaSO3 絮凝物呈现出 疏松多孔的表面结构，对糖汁中悬浮的胶体微粒具有很强的吸附能力。实验数据拟合结果表明，新生CaSO3对糖汁 清净过程符合准二级动力学模型和Temkin吸附等温线。热力学参数显示出CaSO3 的吸附是自发吸热的过程。同时， X CaSO 通过 射线衍射图谱和傅里叶变换红外光谱对絮凝物的成分和结构进行分析，进一步研究了新生 3在糖汁清净 过程中的吸附与包埋机制。 关键词：亚硫酸钙；糖汁清净；形貌和结构；机理 Mechanism of Action of Newly Generated Calcium Sulphite in Sugar Cane Juice Clarification 1,2 1,2,* 1,2 XIANG Fuyou , LI Lijun , CHENG Hao (1. College of Biological and Chemical Engineering, Guangxi University of Science and Technology, Liuzhou 545006, China; 2. Guangxi Key Laboratory of Green Processing of Sugar Resources, Liuzhou 545006, China) Abstract: In this study, we investigated the mechanism of action of calcium sulphite in the clarification of sugar cane juice on the basis of the morphology and structure of calcium sulphite particles. The results revealed that the surface of calcium sulphite particles showed a porous and loose structure, leading to better removal of colloidal particles suspended in sugar cane juice. The kinetic data were described better by the pseudo-second-order kinetic model. The adsorption isotherm was fitted with the Temkin model and thermodynamic parameters suggested that the adsorption process was a spontaneous and endothermic process. Furthermore, the calcium sulphite particles were thoroughly c