原位成像纳米压痕技术研究马尾松管胞细胞壁的力学特性-国际竹藤中心.doc

试样表面对竹材气干密度近红外预测模型精度的影响( 余雁1 江泽慧2 王戈1 覃道春1 1 国际竹藤网络中心，北京，100102，yuyan@icbr.ac.cn 2 中国林业科学研究院，北京，100091, renhq@forestry.ac.cn 摘要： 对应用近红外光谱技术（NIR）和偏最小二乘法（PLS）快速预测毛竹材气干密度的可行性进行了研究，并考虑到竹材构造特点，重点研究从试样不同表面采谱对模型预测精度的影响。为了便于对比，建模过程中光谱数据未经过任何预处理。研究结果表明，试样表面对模型的预测精度有一定影响。从竹材横切面采谱所建模型的预测精度最高，内表面（靠近竹黄面）居中，外表面（靠近竹青面）最差。但如果对竹材的内外表面光谱求平均后建模，则可以显著提高模型的预测精度。随后选择最优模型对随机抽取、未参与建模的17个未知样品的密度进行了预测，预测值与测量值之间的线性相关系数为R2=0.937，表明近红外光谱技术可以快速、准确地预测竹材的气干密度。 关键词：近红外光谱 毛竹 气干密度 模型精度 Effect of Sample Surface on the Accuracy of Near Infrared Predictive Model of Air Dried Density of Bamboo Abstract: This work was undertaken to investigate the feasibility of using near infrared spectroscopy (NIR) and partial least squares regression (PLS) as a tool to rapidly predict the air-dried density of Moso bamboo. Especially, this study focused on the effect of bamboo surface on the accuracy of near infrared predictive model. For comparison, no spectrum treatment procedure was adopted when establishing the NIR models. The results indicated the accuracy of NIR density predictive model was influenced by the sample surface from which NIR spectrums were obtained. The model based on transverse section of bamboo owns the strongest predictive accuracy, followed sequentially by the models based on the inner and outer surface of bamboo. It was also found the predictivel accuracy can be substantially improved if the model was based on the average spectrums obtained from the outer and inner surface. This model was than used to predict the air-dried density of 17 unknown bamboo samples, and a good correlation between the measured and predicted one was obtained. Key words Near-infrared spectrum，Moso bamboo，air-dried density， model accuracy 近红外光谱分析技术（NIR）是一种利用光谱对样品的化学组成、物理性质进行快速测定的分析技术。与其他光谱分析相比，该技术具有快速、安全等特点，已经在食品、农业、石油化工的十几个工业领域得到了广泛的应用，并产生了显著的经济效益（陆婉珍等， 2001）。近几年来，近红外光谱技术在木材科学与加工领域的应用前景得到了广泛关注。大量的研究表明，近红外光谱技术可以快速、无损地预测木材许多物理、化学和力学性质（Hoffmeyer, 1995; Gindl, 2001; Thumm, 2001; Rials, 2002; Schim