国产qz5526碳纤维与东丽t800h碳纤维性能比较-iccm.pdf

国产QZ5526 碳纤维与东丽T800H 碳纤维性能比较 王文义 黄海超 张洪池 姜艺玺 （威海拓展纤维有限公司，山东威海264200） 摘要：近年来，国内碳纤维产业发展快速，从原来的通用型发展到了高强高模型， 但高性能碳纤维大多停留于小批量研发阶段，真正能实现工程化生产的高性能碳 纤维只能达到T800 级。本文通过采用扫描电子显微镜、X 射线衍射仪、透射电 子显微镜、热重分析仪等先进表征仪器，对国产QZ5526 碳纤维与日本东丽T800H 碳纤维的微观结构和力学性能进行对比分析，比较了双方的力学性能、取向度、 孔隙率、表面形貌、断面形貌、层间结合力和耐湿热性等碳纤维应用时最主要的 性能指标。结果表明，QZ5526 碳纤维的拉伸强度、拉伸模量和断裂伸长率均要 高于T800 ，且体密度小于T800H ；QZ5526 和T800H 均为湿法工艺生产，T800H 碳纤维表面沟槽更深，但QZ5526 的孔隙率更大。QZ5526 较T800H 圆度更好， 抗剪切力也更优，但径向分子间结合力的均一性较差，存在较多非晶碳结构导致 断裂伸长率更大；QZ5526 取向度高于T800H ，且QZ5526 石墨微晶发育更加完 全，石墨化程度更高，微晶层间结合力和微晶条带间结合力均要强于T800H ； QZ5526 和T800H 表面所含元素完全相同，所含官能团基本一致，但T800H 表 面活性含氧官能团数量更多，更加易于与树脂的结合。通过以上结论，以期能够 为下游碳纤维复合材料生产单位提供一定参考资料。 关键词：QZ5526 碳纤维；表面形貌；力学性能；孔结构 Comparison on the performance of domestic QZ5526 and Toray T800H carbon fibre Abstract: In recent years, the domestic carbon fiber industry rapid development, from the original model of universal development by high strength ，but high-performance carbon fiber mostly stay in the small batch development. To achieve real engineering production of high-performance carbon fiber, its performance can only achieve T800 level.The microstructure and properties of domestic QZ5526 and Toray T800H carbon fibers were studied by Scanning electron microscopy(SEM), X-ray diffraction(XPS), transmission electron microscopy(TEM), and thermogravimetric analysis(TGA). The mechanical properties, orientation degree, porosity, surface morphology, cross section morphology, bonding strength and heat resistance of the two sides were compared. Research results show that, the tensile strength, tensile modulus and elongation at break of QZ5526 carbon fiber were higher than T800, and the bulk density was less than T800H; Both QZ5526 and T800H were produced by wet process, the surface of T800H carbon fiber was deeper, but the porosity of QZ5526 was lar