化学专业英语3PPT.ppt

Abstract Bismuth telluride (Bi2Te3) nanotubes have been synthesized by a low-temperature aqueous chemical method, using Te powders and BiCl3 as the reactants, NaBH4 as the reductant （还原剂）and NaOH as the pH-controller. Microstructure investigations of powders show that the Bi2Te3 nanotubes have an average diameter of about 100 nm, with the length varying from about 500 nm to 1 μm. The tube walls have a thickness of about 30–40 nm. The growth mechanism of Bi2Te3 nanotubes is discussed in this paper. It is suggested that Bi2Te3 crystals initially grow as flat sheets, and then form a three-dimensional closed shell with the lowest surface energy. The shell must be curved, which could outcome to a Bi2Te3 nanotube at last. 29 Example 2 Preparation of Water-Soluble Magnetite Nanocrystals from Hydrated Ferric Salts in 2-Pyrrolidone: Mechanism Leading to Fe3O4 Zhen Li, Qiao Sun, and Mingyuan Gao* Institute of Chemistry, Chinese Academy of Sciences Zhongguancun, Beiyijie 2, Beijing 100080 (P.R. China) Abstract Water-soluble magnetite (磁铁矿) nanocrystals was synthesized by refluxing （回流冷凝） inexpensive FeCl3·6H2O in 2-pyrrolidone （吡咯烷酮）. Differently sized and shaped magnetite nanocrystals can be obtained simply by varying the reaction time. Carbon monoxide generated during the reaction plays a critical role in the formation of magnetite nanocrystals, since it partly reduces Fe3+ to Fe2+. We believe this novel synthetic approach will not only pave a new way for the preparation of water-soluble magnetite nanocrystals but also provide a new route for mass production of high-quality magnetic nanocrystals, since much more concentrated colloidal （胶体的）solutions can be directly obtained by the current method. 31 Keywords Functions （功能） As the name implies, keywords are the most important words and phrases representative of the theme of the paper, and frequently used in a paper. Readers can find out the theme of the paper by looking at the keywords.