有机合成讲义REARRANGEMENTS2.pptVIP

Halogen, oxygen, sulphur, and nitrogen migration Configuration converted Rupe rearrangement III. Rearrangement to electron-deficient nitrogen The Hofmann, Curtius, Schmidt, and Lossen rearrangement X=H2, Hofmann rearrangement X=N2, Curtius rearrangement X=H-N2+, Schmidt rearrangement X=HOH, Lossen rearrangement Hofmann rearrangement NaBrO Hofmann degradation Curtius rearrangement Preparation of acid azides Schmidt rearrangement Lossen rearrangement Beckmann rearrangement Other reagents: IV. Rearrangement to electron-deficient oxygen Baeyer-Villiger reaction Dakin reaction V. Aromatic arrangeme