wsqxafscourse2b 同步辐射应用新进展课程.pptVIP

EXAFS的产生 当X光照射物质， 在某能量位置处，X光能量正好对应于物质中元素A内壳层电子的束缚能，吸收系数突增，即吸收边位置。中心原子A吸收X后，内层电子由n态激发出来向外出射光电子波，此波在向外传播过程中，受到邻近几个壳层原子的作用而被散射，散射波与出射波的相互干涉改变了原子A的电子终态，导致原子A对X射线的吸收在高能侧出现振荡现象。 单散射理论和多重散射理论 (1) Metastable structures of immisicible FeXCu100-X system induced by mechanical alloying  Significations The method of mechanical alloying can largely increase the solid solubility of immiscible Fe100-xCux alloy. Unique electronic and magnetic properties for Fe-Cu system. The mechanism enhanced solubility of Fe-Cu alloy is not clear. Preparations Alloy omposition Fe100-xCux x= 0, 10, 20, 40, 60, 80, 100. WC balls to the mixed Fe-Cu powder 10 to 1. MA milling rate: about 210 r/min. k3?(k)-k function of Fe100-xCux RDFs of Fe100-xCux alloys Fitting results of the Fe100-xCux samples The structure parameters of Fe100-xCux by fitting the Fe K-edge EXAFS spectra The structure parameters of Fe100-xCux by fitting the Cu K-edge EXAFS spectra Conclusions The local structures around Fe and Cu atoms depend on the initial composition. Fe100-xCux solid solutions x?40, fcc-like structure x?20, bcc-like structure The fitting results indicate that the MA FexCu100-x alloys with x?40 are inhomogeneous supersaturated solid solutions, and there are a fcc Fe-rich and a fcc Cu-rich regions in solid solutions. For lower Cu concentrations with x?20. The evolution of the FT intensities and structural parameters of Fe atoms is identical with those of Cu atoms. This result suggests that the Cu atoms be almost homogeneously incorporated into the bcc Fe-Cu phase. (2) (Ge4Si4) Quantum Well  Phys.Rev.B62，1883( 2000) Stronger optical transitions (0.75, 1.25, 2.31 eV) , grown at 673 K Table Structural Parameters obtained from XAFS data for Ge4/Si4/Si(001) and GexSi1-x alloy Samples coordination type R (nm) N sigma (10-2nm) E(eV) (Ge4/Si4