温差发电用BiCuSeO基热电材料的研究进展.doc

温差发电用BiCuSeO基热电材料的研究 进展 冯波李光强张城诚李亚伟贺铸樊希安 武汉科技大学钢铁冶金及资源利用省部共建教育部 重点实验室武汉科技大学省部共建耐火材料与冶金 国家重点实验室 BiCuSeO基热电材料由于具冇较低的热导率和较高的Seebeck系数，热电性能优 异，丑原料储藏丰富、价格低廉、安全无毒，被认为是一种具有潜在应用前景的 新型热电转换材料。首先介绍了 BiCuSeO基材料的晶体结构、电子结构、热电性 能等基本特征，随后综述了近年来国内外关于BiCuSeO基热电材料的研宄进展， 评述了提高其热电性能的手段，拈Na、Ag、Mg、Ca、Sr、Ba等低价元素掺杂, 铜空位，双空位，带隙调整，晶粒细化，织构化和调制掺杂等。通过电热输运特 性的协同调控，可使其ZT值从未掺杂样品的0. 4左右提高到1. 5。最后从实际 应用的角度出发提出了今后BiCuSeO基热电材料的研宄方向及研宄重点。 关键词： 热电材料;氧硫族化合物;BiCuSeO;热电性能; 冯波：男，研究生，研究方向为BiCuSeO基热电材料 樊希安：男，教授，研允方向为热电材料与器件 E-mail:groupfxa@163. com 基金：国家自然科学基金面上项目51674181) Review of BiCuSeO-based Thermoelectric Materials for Thermoelectric Generation FENG Bo LI Guangqiang ZHANG Chengcheng LI Yawei HE Zhu FAN Xi’ an Key Laboratory for Ferrous Metallurgy and Resources Utilization of Ministry of Education， Wuhan University of Science and Technology; Abstract： BiCuSeO based thermoelectric material with low thermal conductivity, high Seebeck coefficients and excellent thermoelectric properties, rich raw material storage, safety and non-toxicity， are considered to be a novel thermoelectric conversion material with the potential application. We first introduced the basic characteristics of BiCuSeO based compounds such as the crystal structure, electronic structure and thermoelectric properties, then analyzed the preparation methods, and reviewed the means of improving their thermoelectric properties including the doping of low-valance elements such as Na，Ag，Mg，Ca, Sr, Ba, Cu deficiencies, dual vacancies, band gap tuning, grain refinement, texturing and modulation doping etc. The highest ZT value has been increased from \ 4 to 1. 5 by the co-regulation of the electric-thermal transport characteristics. Finally, the research direction for further improvement of the thermoelectric properties of BiCuSeO based materials is summarized. Keyword： thermoelectric materials; oxyselenides; BiCuSeO; thermoelectric properties; 0引言 热电材料能够实现热能和电能的直接转化，在利用高温工业低品位余热和分散 分布式余热进行温差发电方面具有较好的应用前景，已成为当前材料领域的研 究热点。决定材料热电转化效率的关键参数“无