Novel size effect in mesoscopic chemical oscillation systems（侯中怀）.pptVIP

Novel size effect in mesoscopic chemical oscillation systems Zhonghuai Hou (侯中怀) Department of Chemical Physics Hefei National Lab of Physical Science at Microscale University of Science Technology of China 理论化学的三个层面 电子结构理论 量子力学 结果：反应个体的物理化学性质；基本参数 统计行为 统计+唯象 结果：宏观量时空演化行为 －实际体系功能 Nonlinear Chemical Dynamics far-from equilibrium, self-organized, complex, spatio-temporal structures Mesoscopic Reaction System Why Noise/Disorder ? Noise and disorder play constructive roles in nonequilibrium systems Modeling of Chemical Oscillations Macroscopic level: Deterministic, Cont. Modeling of Chemical Oscillations New: Noise Induced Oscillation A model system: The Brusselator Optimal System Size Seems to be common … Internal Noise Stochastic Resonance in a Circadian Clock System J.Chem.Phys. 119, 11508(2003) Analytical study Analytical study Analytical study Analytical study(…) Analytical study(…) Analytical study(…) Analytical study(…) Entropy Production? Entropy Production? Entropy Production? Fluctuation Theorems ! Application to Brusselator Application to Brusselator Summary Noise Induced Oscillation ? Stochastic Modeling is important Optimal system size ? Noise + Nonlinearity Success Analytical Study ? Universality + Underlying mechanism Fluctuation Theorem ? Single Trajectory Thermodynamics + Dynamic Irreversibility Future directions Acknowledgements Supported by: National science foundation (NSF) Details * * 反应动力学 量子+统计 结果：反应势能面，反应途径，速率常数 夸克 美洲豹 Genetic Toggle Switch In E. Coli Nature 2000 Two or more stable states under same external constraints Reactive/Inactive bistabe CO+O2 on Pt filed tip PRL1999 Travelling/Target/Spiral/Soliton … waves PEEM Image CO Oxidation on Pt PRL 1995 Calcium Spiral Wave in Cardiac Tissues Nature 1998 Temporally Periodic Variations of Concentrations Rate Oscillation CO+O2 Nano-particle Catal.Today 2003 Synthetic transcriptional oscillator (Repressilator) Nature 2002 Stat