软枣猕猴桃总酚的可见-近红外漫反射光谱无损检测.PDFVIP

186 2013, Vol.34, No.08 食品科学 ※分析检测 软枣猕猴桃总酚的可见-近红外 漫反射光谱无损检测 1,2 1,2,* 1 2 1 3 3 付 饶 ，辛 广 ，李书倩，张 博，刘长江，王宝刚，冯晓元 (1.沈阳农业大学食品学院，辽宁 沈阳  110 161；2.鞍山师范学院化学与生命科学学院，辽宁 鞍山  114005 ； 3.北京市农林科学院林业果树研究所，北京  100093) 摘  要：应用可见-近红外漫反射光谱在570～1848nm光谱区域内，建立了软枣猕猴桃总酚定量数学模型。实验将 贮藏分三个阶段(采收阶段，贮藏12d ，贮藏24d)进行，通过对比分析不同建模方法得到软枣猕猴桃总酚定标模型。 结果表明，应用偏最小二乘回归算法、一阶导数处理和反相多元离散校正处理所建软枣猕猴桃总酚定标模型的预测 性能较好。定标集样本的交互验证相关系数(RCV)为0.8939 ，交互验证均方根误差(RMSECV)为11.6734mg/ 100g ；预 测集样本的相关系数(RP)为0.8627 ，预测均方根误差(RMSEP)为16.7690mg/ 100g 。研究表明：可见/近红外漫反射光 谱对软枣猕猴桃总酚的快速无损检测具有一定的可行性，但模型精度有待提高。 关键词：可见-近红外漫反射光谱；软枣猕猴桃；总酚 Determination of Total Phenols from Actinidia arguta by Visible and Near-Infrared Diffuse Reflection (VIS/NIR) Spectroscopy 1,2 1,2,* 1 2 1 3 3 FU Rao ，XIN Guang ，LI Shu-qian ，ZHANG Bo ，LIU Chang-j iang ，WANG Bao-gang ，FENG Xiao-yuan (1. College of Food Science, Shenyang Agricultural University, Shenyang 110 161, China ；2. College of Chemistry and Life Sciences, Anshan Normal University, Anshan 114005, China ；3. Institute of Pomology and Forestry, Beij ing Academy of Agriculture and Forestry Sciences, Beij ing 100093, China) Abstract ：The objective of this study was to establish a mathematical model for quantitative determination of total phenols of Actinidia arguta using the near-infrared diffuse reflectance (NIR) spectra in the wavelength range of 570–1848 nm. The experiment was divided into three stages to set the model (harvest stage, storage of 12 days, storage of 24 days), and compared with the different modeling methods. The results