连续变化电导池常数法测定电导率的等效电路分析-中国有色金属学报.PDFVIP

第 18 卷第 3 期 中国有色金属学报 2008 年 3 月 Vol.18 No.3 The Chinese Journal of Nonferrous Metals Mar. 2008 文章编号：1004-0609(2008)03-0551-06 连续变化电导池常数法测定电导率的 等效电路分析及应用 胡宪伟，王兆文，路贵民，石忠宁，曹晓舟，崔建忠，赵兴亮 (东北大学 材料电磁过程研究教育部重点实验室，沈阳 110004) 摘 要：通过分析所得的交流阻抗谱，探讨了采用交流阻抗技术使用连续变化电导池常数法测定溶液和熔盐电导 率的合理实验条件。通过对交流阻抗等效电路进行分析，认为实验电路的交流阻抗过程是电化学极化与浓差极化 共同控制的过程，对于溶液来说，扩散体现出 Warburg 扩散特性，而熔盐的扩散体现出 Gerischer 特性。采用边连 续变化电导池常数公式进行电导率计算时，对应的电路电阻最好选择对所得的 Nyquist 图拟合分析所得的溶液/熔 盐与电极及导线电阻之和。如果考虑拟合误差，也可以采用读取高频率时电路电阻的方法来进行计算。 关键词：连续变化电导池常数法；电导率；等效电路 中图分类号：TF 821 文献标识码：A Equivalent circuit analysis and application for electrical conductivity measurement by continuously varying cell constant technique HU Xian-wei, WANG Zhao-wen, LU Gui-min, SHI Zhong-ning, CAO Xiao-zhou, CUI Jian-zhong, ZHAO Xing-liang (The Key Laboratory of Electromagnetic Processing of Materials, Ministry of Education, Northeastern University, Shenyang 110004, China) Abstract: The alternating current (AC) impedance spectroscopies of continuously varying cell constant (CVCC) experimental conductivity cell system for solution and melts electrical conductivity measurement were analyzed. The AC impedance rational condition for electrical conductivity measurement by CVCC technique was determined. The AC impedance course of the circuit researched is controlled by both of electrochemical polarization and concentration polarization, Warburg diffusion character is represented for AC impedance diffusion course of solution, meanwhile, the melts concentration polarization impedance is assumed to be