重金属元素分析消解技术在镉砷检测中的应用比较-食品研究与开发.PDFVIP

食品研究与开发 ２０17 年 8 月 标准与检测 Ｆood Research And Development 第 38 卷第 16 期 143 DOI ：10.3969/j .issn.1005-6521.2017.16.032 重金属元素分析消解技术在镉 、砷检测中 的应用比较 冯婧 （上海健康医学院，上海 20 1318） 摘 要 ： 选择 高效、准确的样品消解方法是测定重金属元素含量的关键 步骤 ，直接影响检 测结果的准确性和可再现 性。概述干灰化法、湿法消解、高压密闭消解及微波消解方法消解效果的影响 因素 ，及在不同样品 中镉 、砷检测消解时 的应用比较 。结果表 明：灰化温度、时间、消解试剂、消解容器、样品组成等均会影响消解效果 ；4 种 消解方法均可应用 于镉 的检测 ，其 中高压密闭和微波消解效果较好 ；消解砷的检测主要是微波消解和湿法消解 ；海洋生物样品的镉检测 宜使 用敞开体 系消解 ；两种消解方法的联合使 用效果可能优 于单一消解方法。 关键词 ：重金属 ；消解 ；镉 ；砷 Comparison and Application of Digestion Methods of Heavy Metals on Cadmium and Arsenic Determination FENG Jing （Shanghai University of Medicine Health Sciences ，Shanghai 20 1318 ，China ） Ａｂｓｔｒａｃｔ ： The digestion methods in determination of heavy metal were the key step in the analysis process ， which were directly related to the precision and reproducibility. The influencing factors of dry-ashing digestion ， wet digesting ， high -pressure seal digestion and microwave digestion methods were summarized in this paper. The conclusions were as follows ： the detection results were affected by the temperature ， time ， reagents ， digest－ ed vessels and the composition of sample. All four methods could be used in cadmium determination ， but the high-pressure seal and microwave digestion methods were better. The determination of arsenic should adopt wet or microwave digestion. The open -system digestion was more suitable for determination of cadmium in marine organism samples. Two different methods unit could be better than one method alone. Ｋｅｙ