Co掺杂对TiO2光催化剂结构与性能的影响EffectsofDopingCobalt.PDFVIP

2008 年第66 卷 化 学 学 报 Vol. 66, 2008 第14 期, 1725～1730 ACTA CHIMICA SINICA No. 14, 1725～1730 ·研究论文· Co 掺杂对 TiO 光催化剂结构与性能的影响 2 刘秀华* 何小波 傅依备 ( 中国工程物理研究院核物理与化学研究所 绵阳 621900) 摘要 采用溶胶-凝胶法制备了 Co 掺杂的 TiO2 粉末, 利用透射电子显微镜、X 射线光电子能谱、紫外可见光谱和 X 射线衍射技术对粉末进行了表征, 并利用环形光催化反应器对其光催化活性进行了测试. 结果表明, 随焙烧温度的增 加, Co/TiO2 粉末的晶粒尺寸逐渐增大, 升至873 K 时, 钴元素以CoTiO3 形式从TiO2 中析出, 同时TiO2 由锐钛矿型向 金红石型发生转变, 相转变过程中晶格常数a 和c 以及晶胞体积发生收缩. 掺杂钴以后, 粉末的光谱吸收范围被拓展至 可见光, 但是其光催化活性却明显降低. 关键词 钴; 二氧化钛; 粉末; 表征 Effects of Doping Cobalt on the Structures and Performances of TiO2 Photocatalyst LIU, Xiu-Hua* HE, Xiao-Bo FU, Yi-Bei (Institute of Nuclear Physics and Chemistry , China Academy of Engineering Physics, Mianyang 621900) Abstract The Co-doped TiO powders were prepared by the sol-gel method, and characterized by trans- 2 mission electron microscopy, X-ray photoelectron spectroscopy, UV-Vis absorption spectroscopy, and X-ray diffraction. The photocatalytic activities of the powders were also measured by using an annulus photo- chemical reactor. The results showed that the grain size grew gradually with calcination temperatures. When the calcination temperature grew up to 873 K, the cobalt element separated out from TiO as CoTiO . At the 2 3 same time, TiO2 transferred from anatase to rutile phase. In phase transfer, crystal l