土壤与酸性含氟溶液相互作用特征及机理研究-环境科学学报.PDFVIP

第 21 卷第 4 期 环 　境 　科 　学 　学 　报 Vol . 21 ,No . 4 2001 年 7 月 ACTA SCIENTIAE CIRCUMSTANTIAE July ,2001 ( ) 文章编号 2001　　　中图分类号 :S1534 　　　文献标识码 :A 土壤与酸性含氟溶液相互作用特征及机理研究 ( 中国科学院南京土壤研究所 ,南京 　210008) 朱茂旭 ,蒋 　新 ,和文祥 ,王 　芳 ,杨杰文　 摘要 :通过反复多次提取实验方法模拟了酸性含氟溶液与红壤和赤红壤相互作用过程. 结果表明:在相互作用过程中,土壤 中氟含量不同对土壤溶液p H 有明显不同的影响. 当氟含量较低时氟离子对土壤溶液p H 的影响不明显 ; 当浓度较高时则可 大大提高土壤溶液的p H ,缓冲土壤酸化. 在第一次提取中因氟的大量吸附可减少溶液中铝的浓度 ,且氟含量越高铝浓度减 少量越大. 随提取次数增加土壤溶液中铝 、氟浓度同时增加 ,且氟含量越高铝浓度越大 ,其中氟以AlF 络合物为主. 关键词 :酸性溶液 ;氟离子 ;铝 ;AlF 络合 Study on characteristics and mechanisms of interaction bet ween selected soils and fluoridebearing acidic solutions ( ZHU Maoxu , J IANG Xin , HE Wenxiang , WANG Fang , YANGJiewen 　 Institute of Soil Science , Chinese Academy of Sciences , Nanjing 210008) Abstract :An interaction between two selected soils and fluoridebearing acidic solutions was modeled with a prolonged equilibrium extraction experiment . The results showed : that the variation of p H of soil solution are depends strongly on the content of fluoride in soil . When the con centration of fluoride is low , its influence on p H is slight . However the p H of soil solution rises much pronouncedly when the concentration of fluoride is high , which therefore buffers p H further decrease to acidify soil . In the initial extraction , both the concentrations of fluoride and alu minum in soil solutions are relatively low due to a dominant adsorption of fluoride on soil surface . On the contrary , with the increase of the number of extractions both the concentrations of Al and F increased. In soil solution , AlF complex is the dominant