本科毕业论文-染料敏化太阳能电池及其致密层研究精选.docxVIP

湖北大学本科毕业论文（设计）题目染料敏化太阳能电池及其致密层研究姓名学号 2118 专业年级材料化学2012级指导教师职称副教授 2016 年 4 月 26 日目录第一章绪论11.1引言11.2染料敏化太阳能电池（DSSC）21.2.1DSSC及其光阳极致密层研究的发展21.2.2DSSC的结构和原理21.2.3DSSC的相关参数41.3选题的目的及意义5第二章DSSC的制备过程及性能的表征52.1实验材料及相关测试设备52.1.1实验仪器：52.1.2实验药品：52.2DSSC的制备工艺流程62.2.1TiO2溶胶的制备及旋涂62.2.2具有致密层的光阳极制备72.2.3DSSC的组装72.3样品结构分析82.3.1X射线结构分析（XRD）82.3.2扫描电镜分析（SEM）82.3.3原子力显微镜分析（AFM）82.4光电性能测试82.4.1光电转化效率与EIS82.4.2暗电流测试8第三章实验结果分析83.1样品XRD分析83.2样品SEM图93.3AFM分析103.4样品J—V曲线与EIS分析10第四章结论12参考文献I致谢III染料敏化太阳能电池及其致密层研究摘要致密层对染料敏化太阳能电池（DSSC）光电性能的提高具有重要的意义，致密层的引入可以抑制导电子的复合。本文针对染料敏化太阳能电池光阳极材料致密层的制备及其对DSSC性能影响进行了研究，采用溶胶凝胶法制备了TiO2致密层，工艺简单，无需高温高压，且效果突出；得到的溶胶均匀透明，利于旋涂制膜。通过SEM与AFM对其形貌进行了表征，结果表明TiO2致密层表面平整，粒径分布较窄。测试结果表明，引入TiO2致密层后，染料敏化太阳能电池性能得到提升，最佳电池的短路电流密度、填充因子及光电转化效率分别达到12.99 mA/cm2、69.08 % 和6.38 %，相较无致密层的DSSC而言，分别提高了31.08 %、1.04 %和29.94 %。关键词：染料敏化太阳能电池致密层结构表征光电性能分析Dye-sensitized solar cells and its research of compact layerAbstractCompact layer is of great significance to improve the photoelectric properties of dye-sensitized solar cell (DSSC). The introduction of the compact layer can efficentlyinhibit the electron recombination. Focusing on the preparation of compact layers andthe mechanism research, in this article,the sol-gelmentonds were used to fabricated compact layer, which is simple and do not require hightemperature and high reaction pressure. The morphology of TiO2compact layers were characterized via SEM and AFM. The results showed that TiO2 layers wereflat,compact and have narrow particle size distribution. With the introduction ofTiO2 compact layer the photoelectric properties of DSSC wasimproved successfully.Theshort circuit current density, filling factor and and solar energyconversion efficiency of the champion cell reached to 12.99 mA/cm2, 69.08 % and 6.38 %respectively , increased by 31.08 %, 1.04 % and 29.94 %, respectively, comparingto the traditional DSSC without any blocking layers.Key words:dye-sensitised solar cells, compact layer,structuralcharacterization,photoelectric