物理化学Exercise 2-4.docxVIP

Physical Chemistry (I) Exercises 2-4, April 20, 20121 True or false? (a) When an exothermic reaction in a closed system with p-V work only is run under isobaric and adiabatic conditions, . (b) When a substance is in its thermodynamic standard state, the substance must be at 25 ℃. (c) Doubling the coefficients of a reaction doubles its . (d) is zero for . (e) is zero for . (f) is zero for . (g) For a reaction involving only ideal gases, is independent of temperature. (h) .2 For a fixed amount of a perfect gas, which of these statements must be true? (a) U and H each depend only on T. (b) is a constant. (c) for every infinitesimal process. (d) . (e) for a reversible process.3 (This problem is especially instructive.) For each of the following processes deduce whether each of the quantities Q, W, , and is positive, zero, or negative. (a) Reversible melting of solid benzene at 1 atm and the normal melting point. (b) Reversible melting of ice at 1 atm and 0 ℃. (c) Reversible adiabatic expansion of perfect gas. (d) Reversible isothermal expansion of a perfect gas. (e) Adiabatic expansion of a perfect gas into a vacuum (Joule experiment). (f) Joule-Thomson adiabatic throttling of a perfect gas. (g) Reversible heating of a perfect gas at constant p. (h) Reversible cooling of a perfect gas at constant V.1 From the data at 25 ℃:Compute the standard heat of formation of and of.1 True or false? (a) When an exothermic reaction in a closed system with p-V work only is run under isobaric and adiabatic conditions, . (true) (b) When a substance is in its thermodynamic standard state, the substance must be at 25 ℃. (false) (c) Doubling the coefficients of a reaction doubles its . (true) (d) is zero for . (false) (e) is zero for .(true) (f) is zero for . (true) (g) For a reaction involving only ideal gases, is independent of temperature. (false) (h) . (false)T; (b) F; (c) T; (d) F; (e) T; (f) T; (g) F; (h) F2 For a fixed amount of a perfect gas, whi