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溶液诱导化学交联PVA形状记忆回复
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PAPER /softmatter | Soft Matter
Solvent induced shape recovery of shape memory polymer based on chemically
cross-linked poly(vinyl alcohol)
Haiyan Du and Junhua Zhang *
Received 27th October 2009, Accepted 24th March 2010
First published as an Advance Article on the web 17th May 2010
DOI: 10.1039/b922220k
A shape memory polymer based on poly(vinyl alcohol) (SM-PVA) chemically cross-linked with
glutaraldehyde exhibits good temperature responsive shape memory behavior. In the present
investigation, solvent-induced shape memory behavior is observed by immersing this kind of SM-PVA
K in good or poor solvents (including water, DMF, and EG etc.) for PVA. A significant indication of
0
2 shape memory is the decrease of the glass transition temperature (Tg), which is caused by PVA swelling
2
2
2 in certain solvents. Differential scanning calorimetry (DSC), dynamic mechanical analysis (DMA),
9
B
/ swelling equilibrium and bending tests are carried out to find the mechanism behind this interesting
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3
0 phenomenon. Factors that influence the permeation of solvents in the polymer depend on the rate and
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.
0 degree of swelling and whether swelling will occur, which determines the shape recovery ratio in
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:
i
o different solvents. Water can induce shape recovery in a shorter time than organic solvents.
d
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g The structure of water and PVA, and the interaction between them, contribute to the shorter recovery
r
o
0 c
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