D04极端条件材料与器件.pdf

D04. 极端条件材料与器件 分会主席：赖新春、吴卫东、王宇钢、徐文、王志刚 D04-01 压致室温盐水L-VI-VII 结冰相变 孙长庆1,2 1. 长江师范大学 2. 新加坡南洋理工 We show that transiting NaX/H O solutions of 0.016 molar concentration (X = F, Cl, Br, I) and NaI/H O of different 2 2 concentrations into an ice VI phase and then into an ice VII at 298 K proceeding in different ways. The solute-type-resolved critical pressures PC1 and PC2 increases simultaneously in the Hofmeister series order: X = I Br Cl F ∼ 0; comparatively, concentration-resolved PC1 increases faster than the PC2 that remains almost constant at higher NaI/H2O concentration. The PC1 moves along the Liquid-VI phase boundary and merges to PC2 at the Liquid-VI-VII phase junction of 350 K and 3. 05 GPa. Observations confirmed that the solute solvation creates electric fields that lengthen and soften the O:H nonbonds and meanwhile shorten and stiffen the H–O bonds, being the same to molecular undercoordination. Compression ，however，does it oppositely. Therefore，compression recovers the electrification-deformed O:H–O bond first and then proceeds to the phase transitions. The concentration-raised anion-anion interaction weakens the electric field within the hydration shell, which discriminates the effect of NaI/H2O concentration from solute types at an identical concentration. D04-02 拓扑电子材料高压调控研究 杨昭荣 中国科学院强磁场科学中心 D04-03 高压条件下高能炸药相变机制及物性研究 陈军 北京应用物理与计算数学研究所 D04-04 压致诱导新型卤化物钙钛矿材料的结构和光学性质研究 邹勃 吉林大学 金属卤化物钙钛矿材料和有机金属卤化物钙钛矿材料，因其具有较高的光电转换效率引起人们的广泛 关注，其优异的光电性质和低成本的制备前景，进一步促进了金属卤化物钙钛矿材料以及纳米晶体的迅速 发展。但是，它们在水氧等气氛条件下不稳定，极大地限制了其在太阳能电池中的实际应用。因此，为了 进一步推动金属卤化物钙钛矿材料和有机金属卤化物钙钛矿材料的实际应用发展，需要深入了解此类材料 的结构与光电性能之间的关系。利用原位同步辐射XRD 光谱、原位高压拉曼散射光谱、吸收光谱和发光 光谱以及第一性原理计算，能够系统地研究压力诱导金属卤化物钙钛矿材料和有机金属卤化物钙钛矿材料 的结构演变和带隙变化。原位同步辐射XRD 和拉曼实验结