[理学]关于纳米进合成方法的组会报告.ppt

组会报告 2012.12.03 刘欣美 本周工作 Cu2O microcrystals: a versatile class of self-templates for the synthesis of porous Au nanocages with various morphologies. 常见的能谱光谱 Template-free Mainly contains ultrasonication, spray drying or pyrolysis, laser pyrolysis,etc. The features of this method are simplicity of operation, cost effectiveness and lack of elaborate equipment. Disadvantages difficulties in controlling the size and shape of hollow structures. Template-assistant Template-assistant method is one of the most controllable approaches for the synthesis of hollow nanostructures Traditional template-based routes involve the growth of a shell of designed materials on various removable templates.form core–shell composites and subsequently remove the template portions by calcinations or selective etching,generating hollow structures, whose inner structure is largely determined by the size and shape of the templates. Self-templating methods Under these conditions, the newly developed self-templating methods are more attractive. These strategies eliminate the need for heterogeneous growth,making them more convenient to control the sizes and the shapes of the interior void of the products 1.Ostwald ripening process 2. Kirkendall effect 3. galvanic replacement Abstract When the Cu2O microcrystals possess only one type of exposed planes, Au nanoparticles (NPs) are deposited homogeneously on the supports, etching out Cu2O portions in the as-prepared nanocomposites, with porous Au nanocages produced. However, if the Cu2O microcrystals have two kinds of exposed planes, such as (111) and (100), selective deposition of Au NPs was observed. Based on this phenomenon, cuboctahedral and truncated octahedral Au nanoframes were synthesized. The catalytic activity of cubic Au nanocages in the reduction of 4-nitrophenol by sodium borohydride is much higher than that of reported spongy Au nanocrystals Synthesis of Cu2O crystals 1.Cu2O cube 1.0 mL of 0