大面积石墨烯之合成方法与其发展(两岸碳材料-蔡春鸿).ppt

Large-scale Synthesis of Graphene from Chemically Derived Graphene Oxide J. Mater. Chem., 2010,?20, 2277 - 2289 * Chemically Derived Graphene Oxide Goki Eda, Manish Chhowalla, Avd. Mater. 22, 1 (2010) * Graphene oxide(GO): an alternative route toward large production of graphene Advantages: Cost-effective Easy and scalable fabrication Low-temperature (on versatile substrate) Solution-processed (good for application and functionalization) Bottle-neck in developing progress: GO is structural damaged. Require a reduction step and restorattion to graphitic structure. 2. Typical methods on the reduction of GO into graphene : (1) Chemical routes (i.e., Hydrazine soaking) (2) Thermal annealing (H2 at 900-1000oC). Our research destination: Large-area single-layer GO sheet Highly Efficient Restoration of Graphitic Structure in Graphene Oxide M. Chhowalla’s group. ACS NANO (2010) R.S. Ruoff’s group. Nature Nanotech. (2009) * Synthesis of ultra-large graphene oxide monolayers pre-oxidized graphite 120ml H2SO4 +K MnO4(10g) and Stirring 500rpm 20ml 30% H2O2 1:10 HCl and water wash and filtering Centrifugation 3000 rpm The as-prepared GO solution C.Y. Su et al Chem. Mater. 21 (2009) 5674 In chemistry, Hummers’ method was well-known to prepare GO from graphite. In this work, we replaced the first step (oxidation of graphite flakes with H2SO4, P2O5 and K2S2O8) with a bath sonication process. Sonication in H2SO4 for 1-6 hr Natural graphite flakes * Largest graphene oxide monolayer C.Y. Su et al Chem. Mater. 21 (2009) 5674–5680 We have demonstrated that the ultra-large GO monolayers (up to several mm in lateral size) can be obtained by introducing the sonication step in the modified Hummers’ method. GO sheets can be adjusted by the sonication period: 1h sonication: 100 um~ several mm 2h sonication: 20-100 um 6h sonication: 1~5um * Electrical characterization of ultra-large reduced GO monolayers : Transparent Cond