钯镍合金在玻碳电极上电结晶机理citeseerx.pdf

物理化学学报(Wuli Huaxue Xuebao) 1446 Acta Phys. -Chim. Sin. 2011, 27 (6), 1446-1450 June [Article] 钯镍合金在玻碳电极上电结晶机理 岳俊培 杨防祖* 田中群 周绍民 (厦门大学化学化工学院, 固体表面物理化学国家重点实验室, 福建厦门361005) 摘要: 在钯镍合金电解液中, 采用循环伏安和计时安培实验方法, 运用Scharifker 和Hills 模型、Heerman 和 Tarallo 模型揭示钯镍合金的成核机理. 结果表明, 钯镍合金在玻碳电极上发生成核过程. Scharifker 和Hills 模 型分析表明, 钯镍合金更符合扩散控制下的三维生长的连续成核机理. 借助于Heerman 和Tarallo 模型, 拟合得 到钯镍合金的成核和生长的动力学参数. 拟合结果显示, 电位阶跃从-0.85 V 负移至-0.92 V (vs SCE), 钯镍合 -1 -1 4 -2 4 -2 金在玻碳电极上的成核速率从0.83 s 增加到7.71 s , 成核密度数从2.77×10 cm 提高至7.09×10 cm . 关键词: 钯镍合金; 电结晶; 循环伏安; 计时安培曲线 中图分类号: O646 Electrocrystallization of Pd-Ni Alloys on Glassy Carbon Electrode YUE Jun-Pei YANG Fang-Zu* TIAN Zhong-Qun ZHOU Shao-Min (State Key Laboratory of Physical Chemistry of Solid Surfaces, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, Fujian Province, P. R. China) Abstract: Using the Scharifker and Hills model and Heerman and Tarallo model, cyclic voltammetry and chronoamperometry were used to study the nucleation mechanism upon the electrodeposition of a Pd-Ni alloy from an electrolyte. The results show that the electrodeposition of the Pd-Ni alloy onto glassy carbon electrode consisted of nucleation and growth, and the nucleation process according to the Scharifker and Hills model follows three di