银稀土氧化物触头材料的性能有色金属科学与工程.doc

连续还原碳化法制备纳米WC-Co复合粉研究 羊建高12，吕健1，朱二涛1陈颢1，郭圣达1 （1..钨资源高效开发及应用技术教育部工程研究中心，江西 赣州 341000；2湖南顶立科技有限公司，湖南 长沙 410118） 摘 要: 关键词: Preparation of nanophase WC-Co composite powder by continuing reduction --carbonization YANG Jian-gao 12,，ü Jian 1， （1.Engineering Research Center of High-efficiency Development and Application Technology of Tungsten Resources, Ministry of Education, Ganzhou, 341000, China; 2.Advanced Corporation for Materials Equipments, Changsha, 410118, China) Abstract: A traditional method for producing ultra fine WC-Co mixtures begins with tungsten oxides by calcination of APT, and then tungsten powder is prepared in hydrogen by reducing. After that, carbon is introduced, mixed, and those mixtures are carbonized to prepare WC. A wet-milling process is implemented as well, with reduced Co powder, and finally after drying process the WC-Co composite is obtained. For the reason of the complexity of this method and its high cost, it usually results in a production which is not well qualified in composition and particle size distribution, the obtained grain is not good for further refinement either. For the purpose of industry application, a new method, which uses ammonium metatungstate (AMT), soluble cobalt salt, and organic carbon source as the raw materials to produce nanophase WC-Co composite powder, is studied in this paper. In addition, spray drying, calcination, and a low temperature reduction-carbonization process are required. The experiment results show that the appearance of the powder is shell spherical skeleton structure, the WC particles are coated by the Co molecule at the nano level, the component is uniform in molecular size, the particle size is in the range under 100nm. The powder has the character of good fluidity, fine crystal grain and even distribution. Key Words: Nanophase WC-Co composite powder; spray drying; continuing reduction-carbonization  纳米WC-Co复合粉末是制备耐磨耐蚀表面强化材料及超细晶硬质合金的关键材料。。 随着工艺与装备的进步，近年来，出现了一些制备纳米WC-Co复合粉的新方法，如喷雾转换法、氧