原创力文档distinctive morphology effects of porous-sphericalyolk-shellhollow pd-nitrogen-doped-carbon spheres catalyst for catalytic reduction of 4-nitrophenol：（独特的形态学影响porous-sphericalyolk-shellhollow pd-nitrogen-doped-carbon球体4-nitrophenol催化还原的催化剂）.pdfVIP
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distinctive morphology effects of porous-sphericalyolk-shellhollow pd-nitrogen-doped-carbon spheres catalyst for catalytic reduction of 4-nitrophenol：（独特的形态学影响porous-sphericalyolk-shellhollow pd-nitrogen-doped-carbon球体4-nitrophenol催化还原的催化剂）
Journal of Colloid and Interface Science 496 (2017) 465–473
Contents lists available at ScienceDirect
Journal of Colloid and Interface Science
journal homepag e: /locate/jcis
Regular Article
Distinctive morphology effects of porous-spherical/yolk-shell/hollow
Pd-nitrogen-doped-carbon spheres catalyst for catalytic reduction
of 4-nitrophenol
Yu Long ⇑, Yansheng Liu, Ziming Zhao, Sha Luo, Wei Wu, Li Wu, He Wen, Ren-Qi Wang, Jiantai Ma ⇑
State Key Laboratory of Applied Organic Chemistry (SKLAOC), Gansu Provincial Engineering Laboratory for Chemical Catalysis, College of Chemistry and Chemical Engineering,
Lanzhou University, Lanzhou 730000, PR China
g r a p h i c a l a b s t r a c t
a r t i c l e i n f o a b s t r a c t
Article history: Pd-nitrogen-doped-carbon nanocatalysts (Pd-C/N) with different morphologies, such as porous spheres,
Received 12 January 2017 yolk-shell and hollow structures, had been synthesized and compared. The yolk-shell Pd-nitrogen-doped-
Revised 20 February 2017 carbon nanocatalysts (YS-Pd-C/N) and hollow Pd-nitrogen-doped-carbon nanocatalysts (H-Pd-C/N) were
Accepted 21 February 2017
prepared through different etch time using SiO2 spheres as hard-templates. The as-prepared catalysts
Available online 22 February 2017
were characterized thoroughly by TEM, BET, XRD, FT-IR, and XPS. Importantly, the catalysts have moder-
ate BET specific surface area in the range from 200 to 300
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