Graphene-Wrapped Fe3O4 Anode Material for Lithium Ion Batteries-材料合成化学课件PPT.pptVIP

下载本文档

3
0
约2.34千字
约 16页
2018-03-13 发布于浙江
举报
版权申诉

Graphene-Wrapped Fe3O4 Anode Material for Lithium Ion Batteries-材料合成化学课件PPT.ppt

1、本文档共16页，可阅读全部内容。
2、原创力文档（book118）网站文档一经付费（服务费），不意味着购买了该文档的版权，仅供个人/单位学习、研究之用，不得用于商业用途，未经授权，严禁复制、发行、汇编、翻译或者网络传播等，侵权必究。
3、本站所有内容均由合作方或网友上传，本站不对文档的完整性、权威性及其观点立场正确性做任何保证或承诺！文档内容仅供研究参考，付费前请自行鉴别。如您付费，意味着您自己接受本站规则且自行承担风险，本站不退款、不进行额外附加服务；查看《如何避免下载的几个坑》。如果您已付费下载过本站文档，您可以点击这里二次下载。
4、如文档侵犯商业秘密、侵犯著作权、侵犯人身权等，请点击“版权申诉”（推荐），也可以打举报电话：400-050-0827(电话支持时间：9:00-18:30)。
5、该文档为VIP文档，如果想要下载，成为VIP会员后，下载免费。
6、成为VIP后，下载本文档将扣除1次下载权益。下载后，不支持退款、换文档。如有疑问请联系我们。
7、成为VIP后，您将拥有八大权益，权益包括：VIP文档下载权益、阅读免打扰、文档格式转换、高级专利检索、专属身份标志、高级客服、多端互通、版权登记。
8、VIP文档为合作方或网友上传，每下载1次，网站将根据用户上传文档的质量评分、类型等，对文档贡献者给予高额补贴、流量扶持。如果你也想贡献VIP文档。上传文档

Graphene-Wrapped Fe3O4 Anode Material for Lithium Ion Batteries-材料合成化学课件PPT

Graphene-Wrapped Fe3O4 Anode Material for Lithium Ion Batteries Applications for Lithium ion battery High energy density: small volume huge energy High voltage: reduce the number of series battery Good cycle performance: long service life(1000times) No memory effect: charge and discharge at any time Environmental friendly Advantages of Li-ion battery Simple principles of the Li-ion battery Carbon material LiTiO Tin oxide Metal oxide (Co Ni Fe Cu) Compound material Anode material for Li-ion battery Fe3O4 Advantages: High specific-capacity(924mAh/g) Higher potential High electronic conductivity Disadvantages: Severe aggregation Huge volume change What we are doing ? What we are doing ? Step1: synthesis of GNSs Synthesis of the GNS/Fe3O4 material Natural flake graphite powder Oxidated natural flake graphite Oxidated natural flake graphite GNSs oxidation Expansion exfoliation hydrogen alkali 1050℃ Ar atmosphere FeCl3 0.05mol/L 150mL 50mg GNS sonication 1h hydrolysis 353K 12h GNS/ FeOOH dry vacuum 363K 24h Heat-treat 873K Ar atmosphere GNS/Fe3O4 Step2: synthesis of GNS/Fe3O4 composite Synthesis of the GNS/Fe3O4 material Results and Discussion a) X-ray diffraction of the GNS/Fe3O4 Results and Discussion b) Raman spectra of the GNS/Fe3O4 Results and Discussion c) SEM of the GNS/Fe3O4 Commercial Fe3O4 GNS/Fe3O4 Results and Discussion Judged by the a,b and c test above, we did synthesised the GNS/Fe3O4 layer-by-layer structure material expected before Results and Discussion Electrochemical performance of the GNS/Fe3O4 Results and Discussion Why did the GNS/Fe3O4 works well? Prevent the aggregation of Fe3O4 particles Enwrap Fe3O4 particles, reduce detachment(provide buffering space against the volume change) Porosity facilitates ion transportation Synthesised the layer-by-layer structure GNS/Fe3O4 anode material. The GNS/Fe3O4 material has a better electrochemical performance than the commercial Fe3O4 :a capacity of 950mAh/g and a better cycle stability. Analy