Nano-α-Al2O3 by Liquid Feed Flame Spray Pyrolysis-材料合成化学课件PPT.pptVIP

Outline Introduction The status quo of synthesizing nano-α-Al2O3 Why is it difficult to get nano-α-Al2O3 Our method and results Conclusion Introduction Why am I talking about this? From a commercial view there is considerable impetus to develop an economical source of sub-100nm α-Al2O3. Cause this material is widely used ranging from tough prosthetic implants ,to transparent armor ,transparent rather than transluctent sodium vapour lamp envelopes and possibly polycrystalline lasers. The status quo of synthesising nano-α-Al2O3  multiple tons of nano-transition aluminas are produced each year using a variety of gas-phase process,the resulting product by these methods consists mainly of the undesired δ、θ 、 phase and mainly phase Why is it difficult to get nano-α-Al2O3 Complete conversion of t-Al2O3 won’t occur without extensive growth of the particles,thus inhibiting generations of α-Al2O3 nucleis. The vermicular micro structures caused by this phase change inhibit any further densification of these materials. Results Conclusion Nano-α-Al2O3 can be made by LF-FSP, conversion rate is 80-85% Average particle size is 30-40nm,indicating that the powders are mostly single crystals Resulting α-Al2O3 particle surfaces are nearly devoid of hydroxyl groups * * Nano-α-Al2O3 by Liquid Feed Flame Spray Pyrolysis Institute of Solid States Physics Translucent Alumina tube About and α phase: Structure ,how is it formed, What is the relationship between the four phases of Al2O3--- alumina is produced by dehydration of Al(OH)3 at temp of 140-150℃ αphase is thermaldynamic stable,the other transition phases are not thermaldynamic stable.when temp rises the T-alumina will transform into α-alumina,usually at 1200-1400℃. Illustration of grain nucleation and growth of αAl2O3 during phase transformation from θtoα Why? Our method and results Methods: Liquid Feed Flame Spray Pyrolysis(L-FFSP) What is