吡虫啉、啶虫脒生产工艺论述.doc

吡虫啉、啶虫脒生产工艺流程论述 山东农业大学学士论文 PAGE 20 PAGE I 目录 摘要1 英文摘要2 序言3 1 我国农药发展概况3 2 吡虫啉、啶虫脒性质介绍5 2.1 吡虫啉性质介绍5 2.2 啶虫脒性质介绍6 第二章 实习部分7 1 企业介绍7 2 生产原理9 2.1 2-氯-5-氯甲基吡啶合成原理9 2.2 吡虫啉的合成原理11 2.3 啶虫脒的合成原理11 3 生产工艺流程简述11 3.1 二氯生产车间11 3.1.1 双环戊二烯裂解单元11 3.1.2 5-降冰片烯-2-醛合成单元13 3.1.3 2-氰乙基-5-降冰片烯-2-醛合成单元14 3.1.4 2-亚甲基-4-氰基丁醛合成单元15 3.1.5 2-氯-2-氯甲基-4-氰基丁醛合成单元17 3.1.6 2-氯-5-氯甲基吡啶环合单元18 3.2 DMF法合成吡虫啉车间20 3.2.1 流程示意图20 3.2.2 各单元工艺规程20 3.3 啶虫脒的合成22 3.3.1 流程示意图22 3.3.2 各单元工艺规程22 第三章 实习心得及建议24 1 实习心得24 2 个人建议25 参考文献26 致谢28 Content Abstract………………………………………………………………………………1 Abstract in English……………………………………………………………………2 Chapter 1 Preamble…………………………………………………………………3 1 The overview of pesticides in our country……………………………………3 2 The introduction of the features of Idacloprid and Atamiprid……………5 2.1 The introduction of the features of Idacloprid……………………5 2.2 The introduction of the features of Atamiprid………………………6 Chapter 2 Part of Internship…………………………………………………………7 1 Introduction of company………………………………………………………7 2 Principle of the production……………………………………………………9 2.1 Principle of the the production of 2 - chloro -5 – chloromethylpyridine …………………………………………………………………………9 2.2 Principle of the sythesis of imidacloprid………………………………11 2.3 Principle of the sythesis of acetamiprid………………………………11 3 Brief introduction on the processes…………………………………………11 3.1 Production workshop of 2 - chloro -5 – chloromethylpyridine………11 3.1.1 Part of the cracking of dicyclopentadiene……………………11 3.1.2 Part of the synthesis of 5-norbornene-2-aldehyde……………13 3.1.3 Part of the synthesis of 2 - cyanoethyl -5 - norbornene -2 – aldehyde………………………………………………………14 3.1.4 Part of the synthesis of 2-methyl-4-cyanide hyborxybutyric aldehyde………………………………………………………15 3.1.5 Part of the synthesis of 2-chloro-2 -chloromethyl -4 - Cyanide hybroxybutyric aldehyde?………………………………………17 3.1.6 Part of the synthesis of 2 - c