MMM10_γ-Alumina with hierarchically ordered mesopore-macropore from dual templates.pdfVIP

MMM10_γ-Alumina with hierarchically ordered mesopore-macropore from dual templates.pdf

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MMM10_γ-Alumina with hierarchically ordered mesopore-macropore from dual templates

Microporous and Mesoporous Materials 131 (2010) 289–293 Contents lists available at ScienceDirect Microporous and Mesoporous Materials journal homepage: www.elsevi /locate/micromeso c-Alumina with hierarchically ordered mesopore/macropore from dual templates Shao-Wei Bian 1, Yu-Liang Zhang, Hui-Ling Li, Yu Yu, Yan-Lin Song, Wei-Guo Song * Beijing National Laboratory for Molecular Sciences (BNLMS), Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, PR China a r t i c l e i n f o a b s t r a c t Article history: In this paper, we report a procedure using soft/hard dual templates to produce c-alumina with hierarchi- Received 1 October 2009 cally ordered mesopores and macropores (HOMA). Polystyrene spheres colloidal crystals and block co- Received in revised form 5 January 2010 polymer are sequentially used as templates for ordered macropores and mesopores, respectively. Both Accepted 8 January 2010 macropores and mesopores are ordered pores. The wall of cage-like 500 nm macropores is composed Available online 13 January 2010 of ordered mesopores of 3.6 nm, and the walls of mesopores are composed of c-alumina. When loaded with Pt nanoparticles for CO oxidation, Pt/HOMA catalyst shows excellent catalytic properties. Keywords: 2010 Elsevier Inc. All rights reserved. Alumina Macroporous Mesoporous Hierarchically Template

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