鲁西粮食主产区聊城耕地土壤中有机氯农药的污染特征.doc

目 录 前 言 1 1 1 2采样与污染程度分析 2 2.1采集与测定 2 2.1.1布点与采样 2 2.1.2监测项目 2 2.1.3预处理与分析 2 2.2污染程度分析 3 2.2.1分析方法 3 2.2.2污染程度分级及分级标准 3 3结果与讨论 4 3.1 7种有机氯农药的污染程度现状 4 3.2不同土壤质地类型的有机氯农药的残留分析 5 3.3相关性分析 6 3.3.1有机氯农药含量与土壤有机质的相关性分析 6 3.3.2有机氯农药含量与土壤pH的相关性分析 7 3.3.3各有机氯农药之间的相关性分析 7 结论 参考文献 致 谢  摘 要 结合GPS采用网格布点法，对鲁西粮食主产区——聊城市耕地进行了136个样点7种有机氯农药（OCPs）的测定。分别进行了不同土壤类型的OCPs的污染指数计算，并将各OCPs与土壤理化性质之间、各OCPs之间进行了相关性分析。结果表明：聊城市土壤OCPs污染程度从大到小依次为DDTs＞狄氏剂＞艾氏剂＞七氯＞六六六＞异狄氏剂＞六氯苯。各OCPs在粘壤土中均有相对较高的残留。其次是在砂质壤土和砂质粘壤土中，其他土壤质地残留量很低。经相关性分析可知，各有机氯农药与土壤有机质含量、土壤pH之间没有明显的相关性，且各有机氯农药之间的相关程度也很低。 关键词：聊城市；耕地土壤；有机氯农药；土壤类型；相关性分析 Abstract Seven kinds of Organ chlorine Pesticides of 136 soil samples in Liaocheng , which is one of major grain producing areas in West of Shandong province, was detected and analyzed using lattice method. The pollution indexes of Organ chlorine Pesticides in different soil texture are calculated, and the relativity between physical-chemical properties and OCPs contents and the relativity among different Organ chlorine Pesticides are analyzed in this paper. Result showed that, Organ chlorine Pesticides pollution intensity in soil of Liaocheng in turn was showed DDTs＞Sardis reagent＞Aldrin＞Heptachlor＞BHCs＞Sardis reagent vision＞HCBs. Residues of Organ chlorine Pesticides in clay loam are relatively high, and the next are that in sandy loam and Sandy clay loam. Residues of Organ chlorine Pesticides in the other soil are very low. Through relevance analysis, the pertinence of Organ chlorine Pesticides between soils organic matter content, soil pH value are not obvious .The correlation among Organ chlorine Pesticides is also rather low. Key words：Liaocheng city; Arable soil; Organ chlorine Pesticides; Soil texture; Relevance analysis鲁西粮食主产区聊城耕地土壤中有机氯农药的污染特征 前言 有机氯农药（Organ chlorine Pesticides，OCPs）是一类典型的持久性有机污染物（POPs），具有高毒性、高残留性和生物富集性等特点。其生态环境和人体健康的潜在风险近些年来一直受到广泛关注[1-3]。2001年127个国家签署的《关于持久性有机污染物（POPs）的斯德哥尔摩公约》将3大类共12种POPs列入黑名单进行严格限制，有机氯农药（OCPs）即是其中重要的一类[4-5]。美国、日本、中国等国家