学时能源环境化学化学平衡.pptVIP

* * 2、标准电极电势 * ( ) ( ) 原电池的标准电动势： - + - = E E E MF H+ H2(g) Pt 标准氢电极(S.H.E.) 表示为： 电极反应： ( ) g H 2e aq) ( H 2 2 + - + /H H 电对： 2 + ( ) V 000 . 0 /H H 2 = + E * 1.platinized platinum electrode 2. hydrogen gas 3.acid solution with an activity of H+=1 mol/l 4.hydroseal for prevention of oxygen inteference 5.reservoir via which the second half-element of the galvanic cell should be attached * 3、Nernst方程 * F mol 96485C 1 ? = - R T , K mol 8.314J , 时 298.15K 当 1 1 ? ? = = - - 电池反应： J RT lg 2.303 + = J RT ZFE FE lg 2.303 Z MF MF + - = - F J RT E E lg Z 2.303 M