彭金辉微波加热浸出初级富钛料非等温动力学及吸波特性.pdfVIP

微波加热浸出初级富钛料非等温动力学及吸波特性 1 1 1 1 1 1 2 3 彭金辉 ，黄孟阳 ，张正勇 ，张利波 ，张世敏 ，张泽彪 ，黄铭 ，范兴祥 （1.昆明理工大学材料与冶金工程学院 云南 昆明650093；2.云南大学信息学院；3. 昆明贵金属研究所） 摘要：研究了微波加热浸出初级富钛料非等温动力学，并测定了浸出体系的温度和压力曲线及浸出前后 混合液体的吸波特性。动力学研究以铁浸出率为衡量指标，在本试验条件下推导出微波浸出初级富钛料 动力学表观总速率方程为：φ = K ο ⋅ r − 1 ⋅ [HCl ]0 .5056 ⋅ exp ⎛⎜− 44381.8 ⎞⎟；温度和压力曲线表明，浸出 ⎝ RT ⎠ 体系温度和压力的提高，有利于提高铁的浸出率；浸出前后混合液体吸波特性表明，15%盐酸浸出液和 20%盐酸浸出后的混合液都存在吸波特性的突变。 关键词：初级富钛料；非等温动力学；温度和压力曲线；吸波特性 中图分类号：TF803.21 文献标识码：A Non-isothermal Kinetics of Leaching Primary Titanium-rich Materials by Microwave heating and Microwave Absorption Property 1 1 1 1 1 1 PENG Jin-hui ，HUANG Meng-yang , ZHANG Zheng-yong , ZHANG Libo , ZHANG Shi-min , ZHANG Ze-biao , 2 3 HUANG Ming , FAN Xing-xiang (Faculty of Materials and Metallurgical Engineering, Kunming University of Science and Technology, Kunming 650093, China; 2. School of Information Science and Engineering, Yunnan University, Kunming 650091, China; 3. Kunming Institute of Precious Metals, Kunming 650093, China) Abstract: The non-isothermal kinetics of primary titanium-rich material with microwave leaching was investigated. The temperature-pressure curves and microwave absorption property of leaching system were measured. The results of non-isothermal kinetics based on the leaching rate of Fe show that the leaching process can be described as φ = K ο ⋅ r − 1 ⋅ [HCl ]0 .5056 ⋅ exp ⎛⎜− 44381.8 ⎞⎟,the higher temperature and ⎝ RT ⎠