利用氧化铁在可见光激发下产氢.pdfVIP

利用氧化鐵在可見光激發下產氫 Solar Hydroqen Production by Exciting Iron Oxide in Visible Liqht 1 2 Y.F. Ko, Y.H. Su This research attempted to develop a solar hydrogen production technology that will not emit air pollutants and waste thermal energy. Water molecule was splitted into hydrogen and oxygen by synthesizing iron oxide and utilizing solar energy. Iron oxide has high electronic conductivity and light absorption. Iron oxide is an inexpensive material and easily fabricated. Efficiency of photochemical water splitting is up 12 % to 12 %. 關鍵詞： 壹、前　言 (1) 1972 Fuj ishima Honda TiO2 (normal hydrogen electrode, NHE) 1.23eV (2 1) (2-4) (5,6) (7-12) (13) (14) FeO,Fe O ,α-Fe O ,γ- 3 4 2 3 Fe O ,α-FeOOH γ-FeOOHFe O α-Fe O Fe O 2 3 3 4 2 3 3 4 (15) α-Fe O PH 2 3 (16-19) Fe O