喷雾转换法制备纳米WC.doc

不同钨源原料制备WC-Co复合粉的形貌研究 朱二涛1,羊建高1,2,3,邓军旺2,郭圣达3,谭兴龙2,戴煜2,张翔4 （1．江西理工大学 材料科学与工程学院， 江西 赣州 341000） （2．湖南顶立科技有限公司, 湖南 长沙 410118） (3．江西理工大学 工程研究院， 赣州 341000) （4．中南大学 粉末冶金国家重点实验室， 长沙 410083） 摘要：以WC-6%Co为基本成分，计算原料醋酸钴，超纯炭黑、有机碳分别与WO2.72，WO3，APT，AMT配料量，称量后加入装有适量纯水的可倾斜式滚动球磨机，湿磨混匀形成料浆，然后充分搅拌料浆进行喷雾干燥，将喷雾干燥的前驱体粉末煅烧、过筛，称量装舟，推入1100℃通有氢气的高温钼丝炉中制备出WC-6Co复合粉末。结果表明：以WO2.72为原料制备WC-6Co复合粉，粉末粒度在1～45μm,平均粒度为23.38μm；以WO3为原料制备粉末粒度在8～35μm,平均粒度为22.58μm；以APT为原料制备粉末粒度在1～34μm,平均粒度为12.81μm；以AMT为原料制备粉末粒度在3～45μm,平均粒度为17.83μm；粉末球形度由好到差顺序为：WO3、WO2.72、AMT、APT；松装密度由大到小顺序为：WO3、WO2.72、APT、AMT；流动性由好到差顺序为：WO2.72、WO3、APT、AMT；通过测量粉末BET，换算对应WO2.72、WO3、APT和AMT为原料时制备粉末的WC晶粒度分别为400nm，252nm、255nm和26nm 关键词：WO2.72 ；WO3；APT；AMT；喷雾干燥；煅烧；WC-6Co复合粉 中图法分类号：TF123 文献标识码： A Study on morphology of WC-Co composite powders prepared by different W-source materials ZHU Er-tao1, YANG Jian-gao1,2,3, DENG Jun-wang2, GUO Sheng-da1,3, TAN Xing-long2, DAI Yu2，ZHANG Xiang4 (1. School of Materials and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, China) (2. Advanced Corporation for Materials Equipment, Changsha 410118, China) (3. Project Research Institute, Jiangxi University of Science and Technology, Ganzhou 341000, China) （4. State Key Laboratory for Powder Metallurgy Central South University, Changsha 410083, China） Abstract: Using WC-6% Co as the basic ingredient, cobalt acetate, ultra-pure carbon, organic carbon were mixed with WO2.72, WO3, APT and AMT, respectively. After wet milled in the inclinable rolling mill with pure water, the slurry was formed. By sufficiently stirring and then spray drying the slurry，the precursor powders were prepared. After calcined, sieved and weighted, the precursor powders were pushed into 1100℃ high temperature Mo wire furnace with H2. Then WC-6Co composite powders were prepared. The results show that the particle size of the WC-6Co composite powders prepared by using WO2.72 as raw material is 1~45μm, with average particle size of 23.38μm; , they a