巩艳林宇汝欣欣袁宗明陈凯天然气水合物储运.doc

添加剂影响水合物溶液表面张力的实验研究 余汇军 （中国石化集团管道储运分公司 江苏 徐州 221008 ） 摘要：气体水合物具有独特的物化性质，可以开发一系列高新应用技术。但是面临着生成速率慢、生成条件高、实际储气密度较理论值过低这一首要技术瓶颈，所有的应用技术还停留在实验室研究阶段，当前最紧要的即研究水合物生成促进技术。实验采用CTAB、P123、[HMIPS]Ss几种新型添加剂作为水合物溶液的添加剂，测试了在不同温度不同浓度下这几类添加剂对水合物溶液表面张力的影响，以此判断这几类添加剂对水合物生成促进作用与表面张力的定量关系。研究发现其中降低表面张力效果最好的为300mg/kg CTAB，然后依次为500mg/kg P123、300mg/kg [HMIPS]Ss。此研究为今后促进水合物生成研究提供了理论及数据支持。 关键词：水合物；添加剂；浓度；温度 文献标识码：A Research on experiment about additives influenced hydrate solution surface tension Yu Huijun (Sinopec pipeline storage and transportation company Jiangsu Xuzhou 221008) Abstract: The gas hydrate have unique physicochemical properties, and a series of high-tech applications can be developed from these. But facing the primary technological bottlenecks on slow rate, high temperature-pressure condition and the actual low gas storage capacity within hydrate formation, all of the applied technology is still stuck in the laboratory research stage. Therefore, the most critical is the study on hydrate formation promotion technology. In this experiment, using some new additives CTAB、P123、[HMIPS]Ss as the hydrate solution additive, testing the new additives in different temperature and different concentration rained influence on hydrate solution surface tension, to judge the quantitative relationship between additives promotion the process of hydrate generation and surface tension. Research findings 300mg/kg CTAB reduce the surface tension best, then the second is 500mg/kg P123, finally is 300mg/kg [HMIPS]Ss. This study provide theoretical and data support for research on promotion of hydrate generation in t he future. Keyword: hydrate; additive; concentration; temperature 利用水合物独特的物化性质，如储气密度高、生成产生相变且相变温度高、传热系数低等，可以开发一系列高新应用技术。Parker[1]提出利用水合物技术从海水中提取淡水Willson[2]等了用一种化合物作为水合物形成物和萃取剂回收溶液中产品的方法美国哥伦比亚大学Happel[]等了一种新型装置利用水合物可将N2从CH4中分离出来Ohgaki[4]和Ebinuma[]等提出以CO2置换海底水合物沉积层中CH4的设想，并首次用实验证实了将大气中二氧化碳的分离和天然气的开发结合起来的可能性 图1-1 表面张力仪系统示意图 2 实验结果及分析 2.1 浓度对表面张力的影响 图2-