CYCLODEXTRIN IN MEDICAL AND HYGIENIC TEXTILES在医疗卫生用纺织品的环糊精.pptVIP

Use and determination of beta-cyclodextrin on textile substrates Bojana Von?ina University of Maribor, Textile Department, Smetanova 17, 2000 Maribor, Slovenia Structure and dimensions of cyclodextrins Conical structure of ? cyclodextrin ? ? Host–guest complex of ? cyclodextrin and toluene Applications of ? cyclodextrin in textile: Application methods (Surface modification): Exhausting method Pad-batch method Printing Washing Preparation of polymers In fibre spinning Surface modification Encaptulation Grafting of ?-cyclodextrin on cotton using polycarboxylic acid 20 g/l β-CD, 6 g/l BTCA, 3 g/l SHPI 30 g/l β-CD, 6 g/l BTCA, 6 g/l SHPI Quantitative determination of linked ?-CD Gravimetrical method The objective of the present study has been to develop semi-quantitative method for the evaluation of ?-CD fixed onto the textile materials by UV/Vis spectroscopy using alkaline solution of phenolphthalein. ATR FT-IR spectroscopy of nanoencaptulated cotton Mechanism of grafting with policarboxylic acids Conclusions We successfully grafted ?-cyclodextrin onto cellulose substrate by using crosslinking reagent BTCA. In our research the rapid and simple spectroscopic method for determination of micro-amount of cyclodextrin in solution was adopted to determine the amount of ?-cyclodextrin bonded onto the textile material. ITSAPT seminar, Guimaraes, November 2005 ITSAPT seminar, Guimaraes, November 2005 ? ? ? ? Polycarboxylic acids like 1,2,3,4 butanetetracarboxlic acid (BTCA) are well known nonformaldehyde crosslinking reagents. BTCA has four carboxylic acid groups, which can react with hydroxyl groups of cellulose and form stable ester bonds Esterification can occur with heat alone or it can be accelerated by the presence of salts of weak acids, such as sodium hypophosphite (SHPI). Physical properties of cotton fabrics treated with BTCA were comparable with those obtained for cotton treated with the most effective N-methylol reagents such as N, N’-dimethyloldihy