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negative ions formed near the surface in RF and DC discharges负离子在射频和直流放电表面形成.ppt
Surface and volume production of negative ions in a low-pressure plasma E. Stoffels, W.W. Stoffels, V.M. Kroutilina*, H.-E. Wagner* and J. Meichsner*, Department of Physics, Eindhoven University of Technology*Institute for Physics, University of Greifswald Volume production of negative ions(example: low-pressure oxygen plasma) For O- : dissociative attachment to (excited) O2: O2 + e ? O + O- { O2(n), O2(a), O2(b) etc.} For O2- : non-dissociative attachment: O2 + e + X ? O2- + X charge transfer: O- + O2(a) ? O + O2- dissociative attachment to O3: O3 + e ? O2- + O All these processes are inefficient at low pressures! Some factsin radio-frequency plasmas in oxygen Electron/ion density measurements: Negative ion density 1016 m-3 Electron density 1015 m-3 Main ion O- Substantial O2- density: 10-20% Modelling of ion density: calculated measured (about factor 2) less molecular ions expected This is also valid for other electronegative gases Do we miss an important formation process? Extraction of negative ions in RF plasmas Ions are heavy and immobile they “feel” average potential Ions have little energy (room temperature) Positive ions are accelerated by the sheath field Negative ions are confined in the glow No negative ion extraction during normal plasma operation! Mass spectrometry of negative ions problem: extraction In DC discharges - no problem (extraction to a mass spectrometer through an orifice in the anode) In RF discharges - sheath field must be (locally) cancelled Experimental tricks: positively biased extraction orifice (*disturbs plasma) pulsed plasma detection in the afterglow (*no information about “active” discharge) However... We detect negative ions in RF without these tricks! What is the origin of these ions? Negative ions in O2 RF plasmaenergy spectra by QMS Direct negative ion fluxes recorded by mass spectrometer O- detected energy spectra obtained ions arrive at low energies (at most a few eV) potential barrier betwe
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