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Solvent extraction of selected endocrine-disrupting phenols using ionic liquids Graduate Student: D.N. Guo Advisor: M.C. Hsiao content Introduction Experimental Results and discussion Conclusions Introduction(1/5) Liquid-liquid extraction is an effective separation method in analytical science and in chemical industry. Generally speaking, traditional solvent extraction employed partitioning of a solute between two immiscible phases, typically an organic solvent and an aqueous solution. Introduction(2/5) Endocrine-disrupting chemicals (EDCs), also called environmental hormone, have already become a threat to the global eco-system. The alkylphenol, pentachlorophenol, and bisphenol A are common endocrine-disruptors. These compounds are of human health concern due to their potential hazards to human reproductive health. Introduction(3/5) Bisphenol A and pentachlorophenol were applied to produce epoxyresin and phenolics, insecticide and herbicide, respectively. These phenols widely exist in environment. Ionic liquids (ILs) are, as their name implied, liquid ionic media composed of organic ations and inorganic or organic anions, which remain liquid at the temperatures below 100 ?C. Introduction(4/5) In this work, experimental measurements have been performed to determine distribution ratios of endocrine-disrupting phenols between ILs and aqueous solution at different pH values. Five phenols with different chemical structures were chosen: phenol, pentachlorophenol, bisphenol A, 4-octylphenol and 4-nonylphenol. Introduction(5/5) This selection makes it possible to investigate how the nature of anions, length of the alkyl chains on the imidazolium ring and chemical structure of the molecular compounds affect extraction of endocrine-disrupting phenols from aqueous solutions. Experimental Experimental Experimental Results and discussion Results and discussion Results and discussion Results and discussion Conclusion Phenols, including phenol, bisphenol A, pentachlo