Luminescence and luminescent materials发光材料发光材料.pdf

Luminescence and luminescent materials Luminescence and luminescent materials • Introduction • Part I: basic processes • Part II: rare earth luminescence Philippe Smet ‐LumiLab ‐Department of Solid State Sciences ‐Ghent University 2010‐03‐29 Presented at Doctoral School Photonics@be philippe.smet@ugent.be Introduction Luminescence: definition ‘Cold light’: generation of light in a non‐thermal way • Photoluminescence (PL) • Cathodoluminescence (CL) • Electroluminescence (EL) • Chemoluminescence • Bioluminescence • Radioluminescence • Thermoluminescence (TL): false! • Triboluminescence • Sonoluminescence Introduction Types of luminescence (2) • Atomic transitions (Hg, Xe, Na,...) • Organic luminescences (dyes, OLEDs) size • Quantum dots (CdS, CdSe, PbS, ZnS,...) • Doped semiconductors/insulators: localized defects Introduction Types of luminescence: organic LEDs • Flexible devices • First large area prototypes • Issues: stability, lifetime Introduction Types of luminescence: quantum dots CdSe qdots ~1nm ~10nm Bera et al, Materials 2010, 3, 2260‐2345 Luminescence and luminescent materials Part I. Luminescence: basic processes and measurement • Observations • Configuration coordinate diagram • Stokes s