fe ag审审tio2sba审审16的制备及其光催化性能研究 word格式.docxVIP

AbstractWith the rapid development of industry, environment pollution become more and more serious. So how to control and deal with the enviroment pollution have been the most important thing nowadays. Among all the nano-photocatalytic materials, TiO2 become a most promising photocatalyst for its strong oxidation activity, stability and nontoxic. However, TiO2 has two main disadvantages: low quantum yield and low photocatalytic activity. Therefore, how to modify TiO2 in order to increase its photocatalytic activity and extend its range of photo-response spectrum is the key to further utilize in photocatalysis. In this paper, on the foundation of summarizing the development of the modification of Fe, Ag-TiO2 photocatalyst, the novelty Fe, Ag- TiO2/SBA-16 photocatalysts were prepared.SBA-16-supported TiO2 photocatalyst was synthesized by internal hydrolysismethod at different crystallization temperature by using the tri-block copolymer F127 as a template, andtetraethyl orthosilicate (TEOS) as a silica source, tetrabutyl titanate as a titanium source. The synthesized samples were characterized in detail by X-ray diffraction (XRD), N2 adsorption-desorption, transmission electron microscopy (TEM), UV–visible absorption spectra and X-ray photoelectron spectroscopy (XPS). The results indicated that SBA-16 retained the 3D caged-like mesostructure while TiO2 located almost inside the mesoporous channels in form of small crystals with anatase structure. However, the specific surface area and pore volume were decreased with the load of TiO2 increases. The photodecomposition of Rhodamine B (RhB) in aqueous medium was selected to evaluate the photocatalysis performance of TiO2/SBA-16. The results show that 45%TiO2/SBA-16100 had the best photocatalytic activity.The Fe, Ag-TiO2/SBA-16 was prepared with the hydrothermal method withdifferent amounts of TiO2 and Fe, Ag. XRD show that TiO2 particle size is small, crystallization is not high. N2 adsorption-desorption a