ag核c壳多级结构的制备及催化性能分析 word格式.docxVIP

为碳源在分散的P123-Ag+ 结合单元周围碳化形成多孔碳壳，同时还作为还原剂还原银离子制备得银纳米颗粒，最后形成多核Ag@C壳核结构。可以通过P123的质量来调控里面的银纳米颗粒的尺寸。另外，通过催化降解对硝基苯酚对其进行催化性能的测试，展现出优良的催化性能。关键词：纳米银颗粒；核壳结构；银@碳；过氧化氢；P123；催化活性IIPreparationoftheAgcore-Cshell hierarchicalnanostructuresand catalytic performancesAbstractInthelastdecade,metalnanometerialshaveattractedextensiveattentionduetotheirpotential utilityincatalytic,electricalandsensingfields.Thesynthesisofsmallsize,highdispersion,and highnumberdensityofnoblemetalsnanometerialswithwell-controlledshapesandsizesisof greatimportanceinapplicationanddevelopmentofnanometermetalmaterials.However,they arepooratdispersionstabilityandtendtoaggregateinthemedium.Core-shellstructurescan offerprotectiontothemetalcoresaswellasintroducenewpropertiestothehybridstructures. What’smore,core-shellstructuredwithnoblemetalcorepossessexcellentlycatalyticandhigh stabilitycomparedtothebulkmetalnanoparticle.Especiallyforthemulti-corenoblemetalcore shellstructure,alargenumberofsmallsizepackageofnoblemetalnanoparticlesaredispersion intheshell,whichcanpreventnoblemetalnanoparticlesaggregationandoxidationleadingto improve the catalytic efficiency.Sothepreparationofnanometer noblemetalcompositematerial ofcore-shellstructure,especiallythemulti-corecompositehasbeenpaidmoreandmore attention.Inthispaper,multiplecoreAg@Cnonmaterialswerepreparedbybyatemplate methodandonestepmethodaspect.Thestructure,size,morphologyandcatalyticpropertiesof multiplecorenanomaterialshavebeenstudied.Themainresearchcontentsandachievementsin the paperwerelisted as follows:Hollowmultiple-Ag-cores-C-shellnanostructuresthatcomposedofstabilizedAg namopaticlesandporouscarbonshellwerefabricatedfromwell-definedAg@Ccore-shell templatesviaasimultaneoussynthesisandassemblystrategy.Themultiple-Ag-cores-C-shell nanostructurescanbefabricatedbyaredoxreactionbetweentheAg@CtemplatesandH2O2, andtheH2O2serveasasmartetchanttocontrolthedissolvingandoxidizingoftheinitialAg coretoAg+,whichwasdiffusedfromthecoretothecarbonshellandreducedtosmallAg nanopartic