fe2o3bi2o2co3复合纳米材料的合成及其光催化性质的研究 word格式.docxVIP

ABSTRACTIn recent years, bismuth oxide based materials, a novel kind of semiconductor, have been intensively studied due to its special layered structure and outstanding chemical and physical properties. Therefore, the application of bismuth oxide based materials is also very broad, such as solar cells, sensors, ferroelectric materials, nonlinear optical materials and optical catalysis. As a representative member ofAurivillius-related oxide materials, the Bi2O2CO3 is a typical “sillén” phase, in which(Bi2O2)2+ layers and (CO3)2- layers are alternately arranged with the plane of the (CO3)2- group orthogonal to the plane of the layer. The strong intrinsic electric field between the bismuth oxide layer and the carbon oxide layer can effectively promote the separation of photo-generated electron and hole pairs. So, the Bi2O2CO3 photocatalyst shows good photocatalytic activity. In this paper, Bi2O2CO3 photocatalyst has been synthesized by the simply modified hydrothermal method. Then, the effets of the several kinds of organic dyes on its photocatalytic properties have been systematically studied. Afterwards, Bi2O2CO3 has shown good photocatalytic performance in recent years. However, its band gap is relatively large. Therefore, we choose the visible light response Fe2O3 coupled with Bi2O2CO3 to enlarge the light absorb range. Fe2O3/Bi2O2CO3 composite catalyst with the different molar ratios was also synthesized by the facile one-step modified hydrothermal method. The main contents of this paper can be summarized as follows:Bi2O2CO3 photocatalyst has been synthesized by a simply modified hydrothermal method. The as-prepared sample was characterized by XRD, TG-DSC, SEM, TEM, XPS and UV-vis to evaluate the elements, structure, morphology, thermal stability and optical properties. Rhodamine B (RhB), Methyl Orange (MO) and Methylene Blue (MB) were separately used as the model substance to evaluate the photocatalytic activity of the Bi2O2CO3 photocatalyst under the