氢气在煤液化油中的溶解规律及其在煤高温快速液化中作用研究-化学工程与技术专业论文 word格式.docx

lil加入促使氢气参与了液化反应 ，提高了煤液化的总转化率，但增幅有限。表明了加入合适的催化剂可促使氢气参与液化初始阶段的反应 ，不同的催 化剂会产生不同的催化效果，在溶剂具有供氢能力的条件下，洛剂供氢占 优。本文在综合本文的研究结果和本课题组的其他研究成果基础上，分析 给出一种新的煤直接液化反应机理，具体机理模型见图5-9. 该机理模型具 有以下特点:1)该机理将煤液化反应与煤分子结构相关联，在煤高温快速液化的条 件下，最大限度的打破了煤分子结构中连接各结构单元之间的桥键。2) 当反应系统中溶剂的供氢能力好，溶剂量充足时，溶剂的供氢速度快，供 氢量大。在缩聚反应与加氢反应的竞争过程中 ，表现为加氢反应占先，占优。3) 煤液化反应气体的生成来自三个方面，支链脱落、芳香结构开环 形成新的支链的脱落和缩聚反应生成的 气体分子。煤的高温快速液化有效 的限制了后两类气体的生成。关键词:氢气，溶解规律，煤液化油，数学模型，煤高温快速液化飞机THE REGULAR PATTERN OF HYDROGEN DISSOLVED IN COAL LIQUID AND ROLE OF HYDROGEN FOR QUICKCOAL LIQUEFACTION AT HIGH TEMPERATUREABSTRACTCoal direct liquefaction is a kind of efficient coal clean utilization technology. Hydrogen is the feed gas of coal direct liquification process and upgrading of coal liquid，so that 由e thorough study of the regular pattem of hydrogen dissolved in coal liquid has important theoretical and practicalmeanings for coal direct liquification process and upgrading of coal liquid. This paper studies the regular pattem of hydrogen dissolved in coal liquid and the role of hydrogen during QCLHT.To research the regular pattem of hydrogen dissolved in coal liquid，theexperimental device measuring gas solubility in liquid under the high temperature and high pressure was improved. The experimental device added an attemperator in the sampling system can measure hydrogen solubility in some solvents that are solid at normal temperatures. The reliability of device wasverified using methylbenzene as the solvent.This paper measures hydrogenVcksolubility in naphthalene and l-naphthol in using this device for the first time. The regular pattern of hydrogen dissolved in the model components of coal liquid and two-component mixed solvents was studied. The model componentsof coal liquid consist of hexadecane ， methylbenzene ， naphthalene ，tetrahydronaphthalene ，quinolineandI-naphthol. Two-componentmixed solvents consist of different proportions of hexadecane-tetrahydronaphthalene ， hexadecane-quinoline ，tetrahydronaphthalen