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高溫預氧化對鑄鐵耐鋁熱熔損之作用 防蝕工程　第二十八卷第四期　第215 ~ 223 頁　2014 年 12 月 Journal of Chinese Corrosion Engineering, Vol. 28, No. 4, pp. 215 ~ 223 林建瀚、王朝正* 、梁煥昌 Effect of Pre-oxidation at High-temperature on the Thermal Erosion of Cast Iron in Molten Aluminum Chien-Han Lin, Chaur-Jeng Wang*, Huan-Chang Liang Received 28 July 2014; received in revised form 29 October 2014; accepted 15 November 2014 本研究使用FC 250 鑄造片狀石墨鑄鐵及FCD 450 鑄造球狀石墨鑄鐵之商用鑄鐵為底 材，實施750 、850 及900 °C 之高溫預氧化處理後，進行700 °C 的試片靜態和動態旋轉之 商用壓鑄鋁矽合金(ADC12)熱熔損試驗。實驗結果顯示，鑄鐵之氧化層若具有良好的完整 性及附著性，可阻礙鋁鐵之交互擴散，進而提升耐熱熔損能力。片狀石墨在高溫氧化處理 時，氧化並形成連續的孔隙，提供氧氣滲入之路徑，使得氧化物沿片狀石墨晶界向材料內 部快速生長，形成鋁矽熱熔損之阻礙層，因而相對於球狀石墨鑄鐵有較佳的耐鋁矽熱熔損 之能力。 關鍵詞：片狀石墨鑄鐵；球狀石墨鑄鐵；ADC12 ；高溫氧化；鋁湯熱熔損。 ABSTRACT This study uses commercialized cast iron materials such as FC 250 flake graphite cast iron and FCD 450 spheroidal graphite cast iron as the substrate; then pre-oxidized at 750 °C, 850 °C and 900 °C to obtain the surface scales. The static and dynamic thermal erosion tests were performed on oxidized specimen in order to investigate the effect of the oxide layer of the cast irons on the resistance of the thermal erosion in the molten Al-Si-Cu alloy (ADC12) at 700 °C. The results show that the completeness and adhesion properties of the scales are the important factors that would influence the resistance to the thermal erosion. Since the flake graphite formed interconnected cavities after high temperature oxid