锂锶铌磷酸盐玻璃之性质与结构研究-中国矿冶工程学会互动式网站.PDF

鋰鍶鈮磷酸鹽玻璃之性質與結構研究* Additive Effects on the Properties and Structure of Lithium Strontium * Niobium Phosphate Glasses 1 1 1 1 Y.S. Huang S.W. Yung The object of this research is to explore additive effects P O -Nb O -SrO-Li O on the properties and structure of molding glass materials. 2 5 2 5 2 Li OSrO Our study focused on P O -Nb O -SrO-Li O glass system 2 2 5 2 5 2 Nb O P O in which Li O replaced Sr Oto adjust Nb O and P O ratio. 2 5 2 5 2 2 5 2 5 Results showed that (1) the glass refractive index ranged 1.6 1~ 1.85 between 1.61~ 1.85, (2) the transmittance in visible region 80% 80%, and (3) the glass transition temperature 550 . 550 Properties of these glasses meet the standard of molding glasses and are suitable for molding lenses. We used NMR N MR and Raman spectrometer to study the glass structure. 31P 31P NMRLi NMR results showed that the Li ion promoted the dissociation Raman Li2O of phosphate chain s. Therefore, adding Li2O decreased melt ing t emp er atur e and glass tr an sit ion t emp er atur e. Raman Nb Raman spectra examination confirmed that Nb ion in the glass structure thus increase the cross-linking density of the glass network structure. The glasses maintained the network s