第2章 锌锰电池精品.ppt

* The lithium / solublecathode systems (Li /SOC12 and Li/SO2) show the best performance throughout the entire temperature range, with the higher-rate Li/SO2 system having the best capacity retention at the very low temperatures. The zinc / air system has a high energy density at normal temperatures, but only at light discharge loads. The lithium / solid-cathode systems, represented by the Li/MnO2 system, show high performance over a wide temperature range, superior to the conventional zinc anode systems. Figure 7.9 shows an improvement in relative position of the denser, heavier battery systems when compared on a volumetric basis. (Note: As stated earlier, these data are necessarily generalized and present e 锌锰干电池 松下干电池生产工艺流程 2.8 叠层锌锰电池 （自学） 电池组成 (-)Zn/KOH(aq) /MnO2(+) 额定电压：1.5V 可制成二次电池 2.9 碱性锌锰电池(Alkaline manganese dioxide) 碱性锌锰电池(Alkaline manganese dioxide) 锰环-锌膏式结构碱性锌-锰电池制造工艺 卷绕式电池组装工艺流程 锌锰电池产业的现状与未来 我国是世界上电池生产量最大的国家 2007年我国一次电池产量约300.7亿只。其中碱性锌锰电池约82亿只 2008年一次电池产量309.7亿只, 其中碱性锌锰电池超过90亿只 思考题 1.糊式和纸板式锌锰电池有何不同？ 2.ZnCl2型纸板电池与NH4Cl型纸板电池相比具有哪些优势？为什么？ 3.为什么锌锰系列电池适合于小电流间歇放电？ 4. 哪一种MnO2晶体变体阴极极化较小？为什么？ 5.影响锌电极自放电的因素和防治措施 6.碱锰电池比普通锌锰干电池相比具有哪些优势？ 7.叠层锌锰电池中无孔导电膜的作用？为什么要采用无孔导电膜？什么是寄生电池？ 为什么放电时二氧化锰电势持续下降？ * This listing illustrates the performance advantages of the lithium anode batteries. Nevertheless, the conventional primary batteries, because of their low cost, availability, and generally acceptable performance in many consumer applications, still maintain a major share of the market. * Many of the significant advances were made during the 1970–90 period and were stimulated by the concurrent development of electronic technology, the new demands for portable power sources and the support for the space, military and the environment improvement programs. During this period, the zinc / alkaline manganese dioxide batery began to replace the zinccarbon or Leclanche battery as the leading primary battery, capturing the major share of the US market. Environmental c